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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Kilian, Petr
University of St Andrews
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (12/12 displayed)
- 2021Synthetic and structural study of peri -substituted phosphine-arsinescitations
- 2021Synthetic and structural study of peri-substituted phosphine-arsinescitations
- 2021Synthetic and structural study of peri-substituted phosphine-arsinescitations
- 2019A study of through-space and through-bond JPP coupling in a rigid nonsymmetrical bis(phosphine) and its metal complexescitations
- 2018A study of through-space and through-bond JPP coupling in a rigid nonsymmetrical bis(phosphine) and its metal complexescitations
- 2018A study of through-space and through-bond J PP coupling in a rigid nonsymmetrical bis(phosphine) and its metal complexescitations
- 2016Varying the flexibility of the aromatic backbone in half sandwich rhodium(III) dithiolato complexes:a synthetic, spectroscopic and structural investigationcitations
- 2016Rhodium(III) and iridium(III) half-sandwich complexes with tertiary arsine and stibine ligandscitations
- 2016Varying the flexibility of the aromatic backbone in half sandwich rhodium(III) dithiolato complexescitations
- 2016Varying the flexibility of the aromatic backbone in half sandwich rhodium(III) dithiolato complexes : a synthetic, spectroscopic and structural investigationcitations
- 2015Rhodium(III) and iridium(III) half-sandwich complexes with tertiary arsine and stibine ligandscitations
- 2003Phosphorus-selenium heterocycles from the tetraphospholane (PhP) 4 CH 2
Places of action
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article
Rhodium(III) and iridium(III) half-sandwich complexes with tertiary arsine and stibine ligands
Abstract
The syntheses of rhodium(III) and iridium(III) half sandwich complexes containing tertiary arsine and stibine ligands of the form [Cp*M(L)Cl 2 ] (M = Rh, Ir; L = AsEt 3 , AsPh 3 , SbPh 3 ) are reported. These compounds represent infrequent examples of rhodium and iridium metal complexes bearing arsenic or antimony ligands. All new compounds were fully characterised using 1 H and 13 C NMR spectroscopy, mass spectrometry and single crystal X-ray diffraction. DFT calculations show the formation of the complexes from (Cp*MCl 2 ) 2 and EPh 3 (E = P, As, Sb) to be highly exothermic, although the enthalpic driving force is decreasing in the expected sequence P > As > Sb.