| People | Locations | Statistics |
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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Zygadło-Monikowska, Ewa
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (11/11 displayed)
- 2020Magnesium tetraorganyl derivatives of group 13 metals as intermediate products in the synthesis of group 13 metal alkyls and arylscitations
- 2017Synthesis and properties of new carboxyborate lithium salts as electrolytes for lithium-ion batteriescitations
- 2015Synthesis and characterization of lithium-salt complexes with difluoroalkoxyborates for application as lithium electrolytescitations
- 2015Study of ageing effects in polymer-in-salt electrolytes based on poly(acrylonitrile-co-butyl acrylate) and lithium saltscitations
- 2014Lithium electrolytes based on modified imidazolium ionic liquidscitations
- 2013Benzoxaborolate ligands in group 13 metal complexescitations
- 2011Synthesis and characterization of new trifluoroalkoxyborates lithium salts of ionic liquid propertiescitations
- 2008Influence of plasticizer type on the properties of polymer electrolytes based on chitosancitations
- 2004Polymer-in-salt electrolytes based on acrylonitrile/butyl acrylate copolymers and lithium saltscitations
- 2003Effects of inhomogeneity on ionic conductivity and relaxations in PEO and PEO–salt complexescitations
- 2000The effect of solvent and proton donor type on the conductivity and physico-chemical properties of poly(vinylidene fluoride)-based proton-conducting gel electrolytescitations
Places of action
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article
Benzoxaborolate ligands in group 13 metal complexes
Abstract
A series of group 13 metal benzoxaborolates [R2MOB(o-CH2O)(C6H4)]2 [R = tBu, M = Al (2), R = Me, M = Ga (3), R = tBu, M = Ga (4), R = tBu, M = In (5)] were synthesized in reactions of 1,3-dihydro-1-hydroxy-2,1-benzoxaborole (1) with group 13 metal trialkyls. The compounds were characterized by elemental analysis, melting point measurements, 1H, 13C NMR, and IR spectroscopy. The molecular structure of 2–5 was determined by single-crystal X-ray diffraction. The structure of the compounds depends on the kind of metallic center. Reaction of tBu3Al with the benzoxaborole 1 leads to the aluminum derivative 2, similar to typical dialkylaluminum carboxylates, with a central eight-membered B2Al2O4 ring, in which two oxygen atoms of the benzoxaborolate unit are bonded to aluminum atoms. In the presence of gallium and indium trialkyls, the benzoxaborole 1 acts as an alcohol yielding complexes 3–5, similar to dialkylmetal alkoxides, with a central M2O2 (where M = Ga, In) ring. Thermal decomposition of compounds 2 and 4 revealed the liberation of a mixture of organoboron compounds.