| People | Locations | Statistics |
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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Cordes, David Bradford
University of St Andrews
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (29/29 displayed)
- 2024NaLiFe(C2O4)2 : a polyanionic Li/Na-ion battery cathode exhibiting cationic and anionic redoxcitations
- 2024Synthesis, characterization, X-ray Crystallography, Photoluminescence property and DNA binding activity of Co(II) and Ni(II) complexes of a pyrazole containing Schiff-base ligandcitations
- 2024NaLiFe(C 2 O 4 ) 2 :a polyanionic Li/Na-ion battery cathode exhibiting cationic and anionic redoxcitations
- 2023Manipulation of structure and optoelectronic properties through bromine inclusion in a layered lead bromide perovskitecitations
- 2023Synthesis, spectroscopy and structural elucidation of two new CoII and NiII complexes of pyrazole derived heterocyclic Schiff base ligand as potential anticancer and photocatalytic agents
- 2022Synthesis, structure and tunability of zero dimensional organic-inorganic metal halides utilising the m-xylylenediammonium cation: MXD2PbI6, MXDBiI5, and MXD3Bi2Br12·2H2Ocitations
- 2022A two-dimensional manganese-containing coordination polymer for efficient catalysis of the oxygen evolutioncitations
- 2022Structure determination and Hirshfeld surface analysis of new cocrystal and salt forms of 5-aminotetrazole with hydroxy- and nitro-substituted carboxylic acidscitations
- 2022Cadmium(II) Schiff base complex containing 5-fluoroisatin moietycitations
- 2021A simplified extractive metallurgy exercise to demonstrate selective extraction of coppercitations
- 2020A simplified extractive metallurgy exercise to demonstrate selective extraction of coppercitations
- 2019Stable 6H organic-inorganic hybrid lead perovskite and competitive formation of 6H and 3C perovskite structure with mixed A cationscitations
- 2019A Pd3L6 supramolecular cage incorporating photoactive [2.2]paracyclophane Unitscitations
- 2019A single crystal study of CPO-27 and UTSA-74 for nitric oxide storage and releasecitations
- 2018A study of through-space and through-bond JPP coupling in a rigid nonsymmetrical bis(phosphine) and its metal complexescitations
- 2018Synthesis, characterization and antimicrobial activities of Co(III) and Ni(II) complexes with 5-methyl-3-formylpyrazole-N(4)-dihexylthiosemicarbazone (HMPzNHex2)citations
- 2017Blue-to-green emitting neutral Ir(III) complexes bearing pentafluorosulfanyl groups:a combined experimental and theoretical studycitations
- 2017Blue-to-green emitting neutral Ir(III) complexes bearing pentafluorosulfanyl groups : a combined experimental and theoretical studycitations
- 2017Blue-to-green emitting neutral Ir(III) complexes bearing pentafluorosulfanyl groupscitations
- 2016Synthesis and characterization of green-to-yellow emissive Ir(III) complexes of pyridylbenzothiadiazine ligandcitations
- 2016Enhancing the photoluminescence quantum yields of blue-emitting cationic iridium(III) complexes bearing bisphosphine ligandscitations
- 2016Enhancing the photoluminescence quantum yields of blue-emitting cationic iridium(III) complexes bearing bisphosphine ligandscitations
- 2016Peri-substituted phosphorus-tellurium systems – an experimental and theoretical investigation of the P∙∙∙Te through-space interactioncitations
- 2016Synthesis, properties and Light-Emitting Electrochemical Cell (LEEC) device fabrication of cationic Ir(III) complexes bearing electron-withdrawing groups on the cyclometallating ligandscitations
- 2016Synthesis, properties and Light-Emitting Electrochemical Cell (LEEC) device fabrication of cationic Ir(III) complexes bearing electron-withdrawing groups on the cyclometallating ligandscitations
- 2015Peri-substituted phosphorus-tellurium systems – an experimental and theoretical investigation of the P∙∙∙Te through-space interactioncitations
- 2015Peri-substituted phosphorus-tellurium systems – an experimental and theoretical investigation of the P∙∙∙Te through-space interactioncitations
- 2012Reactivity of dipyrimidyldiselenides with [M(PPh3)(4)] and 2-pyrimidylchalcogenolates with [MCl2(diphosphine)] (M = Pd or Pt)citations
- 2012Nanoporous Carbohydrate Metal-Organic Frameworkscitations
Places of action
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article
Reactivity of dipyrimidyldiselenides with [M(PPh3)(4)] and 2-pyrimidylchalcogenolates with [MCl2(diphosphine)] (M = Pd or Pt)
Abstract
<p>Oxidative addition reactions of {SeC4H(4,6-R)(2)N-2}(2) with [M(PPh3)(4)] (M Pt or Pd) in benzene afforded complexes of composition, [Pt{SeC4H(4,6-R)(2)N-2}(2)(PPh3)(2)] (1) and [Pd{eta(2)-SeC4H(4,6-R)(2)N-2} {SeC4H(4,6-R)(2)N-2}(PPh3)] (3) (R H or Me). The former when left in solution dissociated to [Pt {eta(2)-SeC4H(4,6-R)(2)N-2}{SeC4H(4,6-R)(2)N-2}(PPh3)] (2) and PPh3. Treatment of [PtCl2((PP)-P-boolean AND)] ((PP)-P-boolean AND = dppe or dppp) and NaEC4H(4,6-R) 2N2 (for E/R Se/H/Me or Te/Me) gave mononuclear complexes [Pt{EC4H(4,6-R)(2)N-2}(2)((PP)-P-boolean AND)] (4 and 6) (R H or Me, PXP dppe or dppp) which on leaving for recrystallization in dichloromethane/CDCl3 solution resulted in trinuclear chalcogenido-bridged complexes [Pt-3(mu-E)(2)((PP)-P-boolean AND)(3)]center dot 2Cl (E Se or Te) (6). The latter were also formed when [PtCl2((PP)-P-boolean AND)] ((PP)-P-boolean AND = dppe or dppp) was treated with sodium 2-pyrimidyltellurolate. The substitution reactions between [PdCl2((PP)-P-boolean AND)] ((PP)-P-boolean AND = dppe or dppp) and NaEC4H(4,6-R)(2)N-2 (E = Se or Te; R = H or Me) afforded chalcogenido-bridged trinuclear complexes, [Pd-3(mu-E)(2)(PXP)(3)]2Cl (7) ((PP)-P-boolean AND = dppe or dppp). These complexes were characterized by elemental analyses and NMR (H-1, P-31, Se-77, Te-125, Pt-195) spectroscopy. The molecular structures of [Pt(SeC4H3N2)(2)(PPh3)(2)] (1a) and [Pd{eta(2)-SeC4H3N2}{SeC4H3N2}(PPh3)] (3a) were established by single crystal X-ray diffraction analyses. Metal atom in these complexes acquires a distorted squareplanar configuration. (C) 2012 Elsevier B. V. All rights reserved.</p>