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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Blacque, Olivier
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (19/19 displayed)
- 2022[Ru(tmphen)<sub>3</sub>]<sub>2</sub>[Fe(CN)<sub>6</sub>] and [Ru(phen)<sub>3</sub>][Fe(CN)<sub>5</sub>(NO)] complexes and formation of a heterostructured RuO<sub>2</sub>–Fe<sub>2</sub>O<sub>3</sub> nanocomposite as an efficient alkaline HER and OER electrocatalystcitations
- 2022[Ru(tmphen)(3)](2)[Fe(CN)(6)] and [Ru(phen)(3)][Fe(CN)(5)(NO)] complexes and formation of a heterostructured RuO2-Fe2O3 nanocomposite as an efficient alkaline HER and OER electrocatalystcitations
- 2022Platinum(II) and Copper(II) complexes of asymmetric halogen-substituted [NNʹO] ligandscitations
- 2021Synthetic control over polymorph formation in the d-band semiconductor system FeS2citations
- 2021Synthetic control over polymorph formation in the d-band semiconductor system FeS2citations
- 2020Anisotropic character of the metal-to-metal transition in Pr4Ni3O10citations
- 2018Highly Stable and Strongly Emitting N-Heterocyclic Carbene Platinum(II) Biaryl Complexescitations
- 2018Highly stable and strongly emitting N-heterocyclic carbene platinum(II) biaryl complexescitations
- 2017Rationally designed blue triplet emitting gold(III) complexes based on a phenylpyridine-derived frameworkcitations
- 2015Stable and color tunable emission properties based on non-cyclometalated gold(III) complexescitations
- 2014Luminescent monocyclometalated cationic gold(iii) complexescitations
- 2012Dinuclear and mononuclear chromium acetylide complexescitations
- 2012Trans Bis-N-heterocyclic carbene bis-acetylide palladium(II) complexescitations
- 2012(Benzimidazolin-2-ylidene)-AuI-Alkynyl Complexescitations
- 2011Syntheses and photophysical properties of luminescent mono-cyclometalated gold(III) cis-dialkynyl complexescitations
- 2011Alfred Werner's coordination chemistry: new insights from old samplescitations
- 2006Dinitrosyl rhenium complexes for ring-opening metathesis polymerization (ROMP)citations
- 2006Unprecedented ROMP activity of low-valent rhenium-nitrosyl complexes: Mechanistic evaluation of an electrophilic olefin metathesis system.citations
- 2006Unprecedented ROMP activity of low-valent rhenium-nitrosyl complexes : mechanistic evaluation of an electrophilic olefin metathesis systemcitations
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article
Trans Bis-N-heterocyclic carbene bis-acetylide palladium(II) complexes
Abstract
<p>A series of square planar trans bis-N-heterocyclic carbene palladium(II) bis(acetylide) complexes of the type [( <sup>i</sup>Pr <sub>2</sub>-bimy) <sub>2</sub>Pd(C≡C-R) <sub>2</sub>] (bimy = benzimidazolin-2-ylidene) (R = C <sub>6</sub>H <sub>5</sub>, C <sub>6</sub>H <sub>4</sub>F, C <sub>6</sub>H <sub>4</sub>OMe, SiMe <sub>3</sub>, C <sub>4</sub>H <sub>3</sub>S, C <sub>5</sub>H <sub>4</sub>N, C <sub>6</sub>H <sub>4</sub>C≡CC <sub>6</sub>H <sub>5</sub> and 1-pyrene) were prepared by the addition of the corresponding lithium acetylides to the starting ( <sup>i</sup>Pr <sub>2</sub>-bimy) <sub>2</sub>PdBr <sub>2</sub> complex in good to modest yields. The molecular structures of ( <sup>i</sup>Pr <sub>2</sub>-bimy) <sub>2</sub>Pd(C≡C-C <sub>6</sub>H <sub>5</sub>) <sub>2</sub> (1) and [( <sup>i</sup>Pr <sub>2</sub>-bimy) <sub>2</sub>Pd(C≡C-SiMe <sub>3</sub>) <sub>2</sub>] (4) were determined by single-crystal X-ray diffraction studies. UV/vis absorption studies reveal significant spectral changes depending on the nature of the acetylide ligands bound to the palladium center.</p>