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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Bardeau, Jean-François
Université d'Orléans
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (26/26 displayed)
- 2024Green Luminescence in Zero-Dimensional Lead bromide hybrid material (C5H9N3)2PbBr6: Experimental and Theoretical Studiescitations
- 2023In situ mapping of biomineral skeletal proteins by molecular recognition imaging with antibody-functionalized AFM tipscitations
- 2023Quantitative PEEM and Raman study of nanorough Au SERS-Active substrates for molecular sensing applicationscitations
- 2023One-step electrochemical elaboration of SnO2 modified electrode for lead ion trace detection in drinking water using SWASVcitations
- 2022Synthesis, structural and electrical characterization of a new organic inorganic bromide: [(C3H7)4N]2CoBr4citations
- 2021Phase diagram and transition temperatures in the system (T-T’) La2-xNdxCuO4 (x ≤ 0.5)citations
- 2019Antibiofilm Activity of Polyamide 11 Modified with Thermally Stable Polymeric Biocide Polyhexamethylene Guanidine 2-Naphtalenesulfonatecitations
- 2017Unexpected magnetic properties explained by the homogeneity of mixed ferritescitations
- 2016Structural behavior of laser-irradiated γ-Fe 2 O 3 nanocrystals dispersed in porous silica matrix : γ-Fe 2 O 3 to α-Fe 2 O 3 phase transition and formation of ε-Fe 2 O 3citations
- 2016Structural behavior of laser-irradiated γ-Fe 2 O 3 nanocrystals dispersed in porous silica matrix : γ-Fe 2 O 3 to α-Fe 2 O 3 phase transition and formation of ε-Fe 2 O 3citations
- 2016Understanding of the mechanical and structural changes induced by alpha particles and heavy ions in the French simulated nuclear waste glasscitations
- 2015The Inhibitive Effect of Cerium Carbonate on the Corrosion of Brass in 3% NaCl Solutioncitations
- 2015Experimental evidence of ultrathin polymer film stratification by AFM force spectroscopycitations
- 2015The effect of temperature on carbon steel corrosion under geological conditionscitations
- 2015Full-field and contact-less topography of nanometric thin films based on multiwavelength interferometrycitations
- 2014Assignment of Raman-active vibrational modes of tetragonal mackinawite: Raman investigations and ab initio calculationscitations
- 2014Carbon steel corrosion in clay-rich environmentcitations
- 2014Magnetic interactions in γ-Fe 2 O 3 @SiO 2 nanocompositescitations
- 2014The Corrosion Behavior of Carbon Steel in Sulfide Aqueous Media at 30 degrees Ccitations
- 2013A Preliminary Investigation of the ISG Glass Vapor Hydrationcitations
- 2013Impact of a sulphidogenic environment on the corrosion behavior of carbon steel at 90 °Ccitations
- 2013Insight into the mechanism of carbon steel corrosion under aerobic and anaerobic conditionscitations
- 2012Insights into the Mechanism Related to the Phase Transition from γ-Fe2O3 to α-Fe2O3 Nanoparticles Induced by Thermal Treatment and Laser Irradiationcitations
- 2011Site-Selective Surface Modification Using Enzymatic Soft Lithographycitations
- 2008Morphology and Glass Transition of Thin Polylactic Acid Films
- 2005Metal-insulator transition in thin films of RxR ' 1-xNiO3 compounds: DC electrical conductivity and IR spectroscopy measurementscitations
Places of action
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article
Understanding of the mechanical and structural changes induced by alpha particles and heavy ions in the French simulated nuclear waste glass
Abstract
Borosilicate glasses are considered for the long-term confinement of high-level nuclear wastes. External irradiations with 1 MeV He+ ions and 7 MeV Au5+ ions were performed to simulate effects produced by alpha particles and by recoil nuclei in the simulated SON68 nuclear waste glass. To better understand the structural modifications, irradiations were also carried out on a 6-oxides borosilicate glass, a simplified version of the SON68 glass (ISG glass). The mechanical and macroscopic properties of the glasses were studied as function of the deposited electronic and nuclear energies. Alpha particles and gold ions induced a volume change up to −0.7% and −2.7%, respectively, depending on the glass composition. Nano-indentations tests were used to determine the mechanical properties of the irradiated glasses. A decrease of about −22% to −38% of the hardness and a decrease of the reduced Young's modulus by −8% were measured after irradiations. The evolution of the glass structure was studied by Raman spectroscopy, and also 11B and 27Al Nuclear Magnetic Resonance (MAS-NMR) on a 20 MeV Kr irradiated ISG glass powder. A decrease of the silica network connectivity after irradiation with alpha particles and gold ions is deduced from the structural changes observations. NMR spectra revealed a partial conversion of BO4 to BO3 units but also a formation of AlO5 and AlO6 species after irradiation with Kr ions. The relationships between the mechanical and structural changes are also discussed