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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Delevoye, Laurent
French National Centre for Scientific Research
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (13/13 displayed)
- 2023Examining a Year-Long Chemical Degradation Process and Reaction Kinetics in Pristine and Defect-Passivated Lead Halide Perovskitescitations
- 2023Examining a Year-Long Chemical Degradation Process and Reaction Kinetics in Pristine and Defect-Passivated Lead Halide Perovskitescitations
- 2023Role of molybdenum on the structure and properties of A2O-P2O5-MoO3 (A = Na, Ag, Rb, Cs) glassescitations
- 2022Understanding the Mechanochemical Synthesis of [Cu(Cl)(NHC)] Complexes using Solid-State NMR Spectroscopy
- 2020Defect Passivation via the Incorporation of Tetrapropylammonium Cation Leading to Stability Enhancement in Lead Halide Perovskitecitations
- 2011NMR investigation of the crystallization mechanism of LaF3 and NaLaF4 phases in aluminosilicate glasses
- 2011Synthesis, crystal and electronic structures, and magnetic properties of LiLn9Mo16O35 (Ln = La, Ce, Pr, and Nd) compounds containing the original cluster Mo16O36.citations
- 2010New insights into oxygen environments generated during phosphate glass alteration: a combined 17O MAS and MQMAS NMR and first principles calculations study.citations
- 2008Structure and nonlinear optical properties of sodium–niobium phosphate glassescitations
- 2007Structure–property relationships in phase separated borosilicate glasses containing P2O5
- 2006Tin and alkalli chlorides conversion into phosphates and their vitrification into silicate glassescitations
- 2004NMR and Mössbauer characterization of tin(II)-tin(IV)-sodium phosphate glassescitations
- 2004NMR and Mössbauer characterization of tin(II)–tin(IV)–sodium phosphate glassescitations
Places of action
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article
Role of molybdenum on the structure and properties of A2O-P2O5-MoO3 (A = Na, Ag, Rb, Cs) glasses
Abstract
Molybdenum phosphate glasses are materials of interest for nuclear waste storage and solid-state electrolytes, amongst others. Thermal and electrical properties of vitreous molybdophosphates are highly dependent on molybdenum local environment while for example the coordination of this transition metal is still a matter of discussion. The structure of glasses of following composition, xMoO3-(100-x)APO3 (with A = Ag, Na, Rb and Cs) was investigated by means of 31P and 95Mo Nuclear Magnetic Resonance spectroscopy. The structural information was used to better understand the evolution of thermal properties as a function of the molar fraction of MoO3. Particular attention was paid to the crystallization mechanism, studied by X-ray Diffraction, High Temperature Environmental Scanning Electronic Microscopy and Kissinger model, highlighting the formation of a molybdate network (Mo-O-Mo bonds).