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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Zeidler, Anita
University of Bath
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (30/30 displayed)
- 2024Pressure dependent structure of amorphous magnesium aluminosilicatescitations
- 2023Mapping the structural trends in zinc aluminosilicate glassescitations
- 2022Relationship between atomic structure and excellent glass forming ability in Pd 42.5 Ni 7.5 Cu 30 P 20 metallic glasscitations
- 2022Structure and related properties of amorphous magnesium aluminosilicatescitations
- 2022Structure and related properties of amorphous magnesium aluminosilicatescitations
- 2022Relationship between atomic structure and excellent glass forming ability in Pd42.5Ni7.5Cu30P20 metallic glasscitations
- 2021Structure of crystalline and amorphous materials in the NASICON system Na1+xAlxGe2-x(PO4)3citations
- 2021Structure of crystalline and amorphous materials in the NASICON system Na 1+x Al x Ge 2- x (PO 4 ) 3citations
- 2021Structure of crystalline and amorphous materials in the NASICON system Na1+xAlxGe2- x(PO4)3citations
- 2021Detailed structural analysis of amorphous Pd40Cu40P20: Comparison with the metallic glass Pd40Ni40P20 from the viewpoint of glass forming abilitycitations
- 2021Detailed structural analysis of amorphous Pd 40 Cu 40 P 20 :Comparison with the metallic glass Pd 40 Ni 40 P 20 from the viewpoint of glass forming abilitycitations
- 2019Partial structure investigation of the traditional bulk metallic glass Pd40Ni40P20citations
- 2019Ordering on different length scales in liquid and amorphous materialscitations
- 2019Structure of the intermediate phase glasses GeSe3 and GeSe4citations
- 2019Partial structure investigation of the traditional bulk metallic glass Pd40Ni40 P20citations
- 2017Topological Ordering and Viscosity in the Glass-Forming Ge-Se System: The Search for a Structural or Dynamical Signature of the Intermediate Phasecitations
- 2017Structure of rare-earth chalcogenide glasses by neutron and x-ray diffractioncitations
- 2016Pressure-driven transformation of the ordering in amorphous network-forming materialscitations
- 2015Pressure-dependent structure of the null-scattering alloy Ti 0.676 Zr 0.324citations
- 2015Networks under pressurecitations
- 2015Pressure-dependent structure of the null-scattering alloy Ti0.676Zr0.324citations
- 2015Networks under pressure:the development of in situ high-pressure neutron diffraction for glassy and liquid materialscitations
- 2014A combination of anomalous x-ray scattering and neutron diffraction for structural characterizations of Zr63Ni25Al12 metallic glasscitations
- 2013Fragile glass - formers reveal their structural secrets
- 2013Identifying and characterising the different structural length scales in liquids and glasses: an experimental approachcitations
- 2012Structural Transformations on Vitrification in the Fragile Glass-Forming System CaAl 2 O 4citations
- 2012A partial structure factor investigation of the bulk metallic glass Zr63Ni25Al12 as studied by using a combination of anomalous x-ray scattering and reverse Monte Carlo modelingcitations
- 2011Structure of eutectic liquids in the Au-Si, Au-Ge, and Ag-Ge binary systems by neutron diffractioncitations
- 2010Structure of liquid and glassy ZnCl2citations
- 2009Establishing the structure of GeS2 at high pressures and temperatures: a combined approach using x-ray and neutron diffractioncitations
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article
Relationship between atomic structure and excellent glass forming ability in Pd42.5Ni7.5Cu30P20 metallic glass
Abstract
To understand the relation of the glass-forming ability (GFA) to the local atomic configurations of a<br/>Pd42.5Ni7.5Cu30P20 (PNCP) metallic glass having the best GFA at present, the local structures were investigated by<br/>combining data obtained from anomalous X-ray scattering, X-ray and neutron diffraction, and applying reverse Monte Carlo modeling. By comparing the results of PNCP with Pd40Ni40P20 (PNP) and Pd40Cu40P20 (PCP) having a slightly and much worse GFAs, respectively, characteristic features were observed in the hyper-ordered atomic structures. Firstly, the concentration inhomogeneity of Ni/Cu in PNCP is larger than that of Ni in PNP and Cu in PCP. Secondly, a Voronoi tessellation showed that the fraction of pure icosahedral arrangements around the Cu atoms increases significantly in PNCP by adding icosahedral-preferred Ni atoms in PCP. Finally, a persistent homology (PH) analysis reveals the largest intermediate-size Cu PH rings in PNCP among the PH rings in these Pd-based BMGs. The structural heterogeneity for the excellent GFA of PNCP would be considered by an incompatible mixture of specific Pd-P configurations and icosahedral clusters around the secondary Ni and Cu metals.