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Allix, Mathieu
Conditions Extrêmes et Matériaux Haute Température et Irradiation
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (52/52 displayed)
- 2024Crystallization Mechanisms in New Bismuth Borotellurite Glass-Ceramicscitations
- 2024Microstructural insights on lithium aluminum silicate (LAS) glass ceramicscitations
- 2024Crystallization and luminescence properties of Er/Yb-doped glass-ceramics based on A2O-ZnO-SiO2 system (A = Li, Na, K, Cs)citations
- 2024Determination of the Na$_3$AlF$_6$ –Y$_2$O$_3$ Phase Diagram and Its Implications for Low-Temperature YAG/Nd:YAG Synthesis
- 2024Broadband luminescence of Ni2+-doped Zn(GaxAl1−x)2O4-based glass–ceramicscitations
- 2024Realization of extreme nonstoichiometry in gadolinium aluminate garnet phosphors by nonequilibrium synthesis
- 2024Sintering of lixiviated nano glass-ceramics: An original route to elaborate transparent ceramicscitations
- 2024Realization of Extreme Nonstoichiometry in Gadolinium Aluminate Garnets by Glass Crystallization Synthesiscitations
- 2024Crystallization and luminescence properties of Er/Yb-doped glass-ceramics based on A 2 O-ZnO-SiO 2 system (A =citations
- 2024Crystallization in the TeO2 - Ta2O5 - Bi2O3 system: from glass to anti-glass to transparent ceramiccitations
- 2023Towards new zero-thermal-expansion materials: Li-free quartz solid solutions stuffed with transition metal cationscitations
- 2023Oxidation and coordination states assumed by transition metal dopants in an invert ultrabasic silicate glasscitations
- 2023Crystallization of glass materials into transparent optical ceramicscitations
- 2023Key melt properties for controlled synthesis of glass beads by aerodynamic levitation coupled to laser heatingcitations
- 2023Structural environment influence on Faraday Effect in Tb 3+ and Pr 3+ co-doped Fluorophosphate Glass and Glass-ceramics containing TbOF nanocrystalscitations
- 2023Experimental evidence concerning the significant information depth of X-ray diffraction (XRD) in the Bragg-Brentano configurationcitations
- 2022Towards new zero-thermal-expansion materials: Li-free quartz solid solutions stuffed with transition metal cations
- 2022The role of fluorine in high quantum yield oxyfluoride glasses and glass-ceramicscitations
- 2022Crystallization of glass materials into transparent optical ceramicscitations
- 2022Glass formation and devitrification behavior of alkali (Li, Na) aluminosilicate melts containing TiO2citations
- 2022Persistent luminescence of Eu/Dy-doped Sr 2 MgSi 2 O 7 glass-ceramics processed by aerodynamic levitationcitations
- 2021Non-Isothermal Decomposition as Efficient and Simple Synthesis Method of NiO/C Nanoparticles for Asymmetric Supercapacitorscitations
- 2020A comprehensive study of the glass/translucent anti-glass/transparent ceramic structural ordering in the Bi2O3Nb2O5–TeO2 systemcitations
- 2020La2Ga3O7.5: a metastable ternary melilite with a super-excess of inter- stitial oxide ions synthesized by direct crystallization of the meltcitations
- 2020New KNbTeO6 transparent tellurate ceramicscitations
- 2019Deconvolution method of $^{29}$Si MAS NMR spectra applied to homogeneous and phase separated lanthanum aluminosilicate glassescitations
- 2019Highly Transparent Fluorotellurite Glass-Ceramics: Structural Investigations and Luminescence Propertiescitations
- 2019SOLID STATE NMR INVESTIGATION OF TITANIUM'S ROLE ON THE HYDRATION OF INDUSTRIAL SLAGS: A MODEL GLASS STUDY
- 2019Persistent energy transfer in ZGO:Cr 3+ ,Yb 3+ : a new strategy to design nano glass-ceramics featuring deep red and near infrared persistent luminescencecitations
- 2019Properties, structure and crystallization study of germano-gallate glasses in the Ga2O3-GeO2-BaO-K2O systemcitations
- 2018Novel transparent glass-ceramic fiber obtained by the powder-in-tube technique
- 2018First transparent oxide ion conducting ceramics synthesized by full crystallization from glasscitations
- 2017Local Disorder and Tunable Luminescence in $Sr_{1– x /2}$$Al_{2– x}$$Si_{x}$$O_{4}$ (0.2 ≤ x ≤ 0.5) Transparent Ceramicscitations
- 2017Ytterbium-doped oxyfluoride nano-glass-ceramic fibers for laser coolingcitations
- 2017Second harmonic generation in germanotellurite bulk glass-ceramicscitations
- 2016Structure determination of Ba$_5$ AlF$_{13}$ by coupling electron, synchrotron and neutron powder diffraction, solid-state NMR and ab initio calculationscitations
- 2016Transparent polycrystalline SrREGa 3 O 7 melilite ceramics: potential phosphors for tuneable solid state lightingcitations
- 2015Transparency through Structural Disorder: A New Concept for Innovative Transparent Ceramicscitations
- 2015Transparency through Structural Disorder: A New Concept for Innovative Transparent Ceramicscitations
- 2015Phosphorus speciation in dicalcium silicate phases: Application to the basic oxygen furnace (BOF) slagcitations
- 2014Influence of Alteration Solutions on the Chemical Durability of the Zerodur Glass-Ceramic: Structural Investigationcitations
- 2013Perfectly Transparent Sr3Al2O6 Polycrystalline Ceramic Elaborated from Glass Crystallizationcitations
- 2013Perfectly Transparent Sr3Al2O6 Polycrystalline Ceramic Elaborated from Glass Crystallizationcitations
- 2013Synthesis and structure determination of CaSi1/3B2/3O8/3, a new calcium borosilicatecitations
- 2013Control of selective silicate glass coloration by gold metallic nanoparticles: structural investigation, growth mechanisms, and plasmon resonance modelizationcitations
- 2013Pulsed laser deposited amorphous chalcogenide and alumino-silicate thin films and their multilayered structures for photonic applicationscitations
- 2010Similar behaviors of sulfide and selenide-based chalcogenide glasses to form glass-ceramicscitations
- 2010Synthesis and characterization of chloro-sulphide glass-ceramics containing neodymium(III) ionscitations
- 2009Behaviour of ruthenium dioxide particles in borosilicate glasses and meltscitations
- 2008Controlled crystallization in Ge-(Sb/Ga)-(S/Se)-MX glasses for infrared applicationscitations
- 2008Modular construction of oxide structures-compositional control of transition metal coordination environmentscitations
- 2008Optical and Mechanical Properties of Glasses and Glass-Ceramics Based on the Ge-Ga-Se Systemcitations
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article
Glass formation and devitrification behavior of alkali (Li, Na) aluminosilicate melts containing TiO2
Abstract
The impact of TiO2 additions on the quenchability of melts derived from the stoichiometry of spodumene (LiAlSi2O6), eucryptite (LiAlSiO4) and nepheline (NaAlSiO4) was investigated by containerless melting. The results reveal a compositional dependence (Al2O3/SiO2 and M2O/Al2O3 ratios, M = Na or Li) of the role of TiO2 during devitrification. Amorphous samples incorporating up to 10 mol% TiO2 could be produced, above which devitrification invariably took place. Interaction of TiO2 with other glass components (such as Al2O3 and Na2O in nepheline glass) perceivably reduced glass stability, while eucryptite and spodumene glasses appeared only affected to the extent to which nanosized TiO2 polymorphs (TiO2(B), anatase and rutile) served as heterogeneous nucleation sites for quartz solid solutions, in which we inferred a substantial incorporation of Ti4+. A reduction in SiO2 content and a preference for peraluminous compositions stand out as viable compositional strategies to foster the glass-forming ability of TiO2-rich aluminosilicate melts.