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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Veiga, João Pedro
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (12/12 displayed)
- 2020Testing the feasibility of titanium dioxide sol-gel coatings on portuguese glazed tiles to prevent biological colonizationcitations
- 2018Thermal characteristics and crystallization behavior of zinc borosilicate glasses containing Nb2O5citations
- 2017An experimental approach for smelting tin ores from Northwestern Iberiacitations
- 2016Formation and crystallization of zinc borosilicate glassescitations
- 2014Synthesis of Niobium Doped Zinc Borosilicate Glass-ceramics
- 2013Rare-earth doped phosphate glasses
- 2013Optical and structural characterization of samarium and europium-doped phosphate glassescitations
- 2013Effect of Phosphogypsum on the Clinkerization Temperature of Portland Cement Clinkercitations
- 2012Sintering,Crystallization and Dielectric Behavior of Barium Zinc Borosilicate Glasses - Effect of Barium Oxide substitution for Zinc Oxidecitations
- 2012Degradation of dental ZrO2-based materials after hydrothermal fatigue. Part I: XRD, XRF, and FESEM analysescitations
- 2010Characteristics Of The Blast Furnace Dust In Accordance With The Conditions Imposed By The Valorisation Solution
- 2010Artificial Aging of Zr-based Dental Materials - A Pilot Study
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article
Thermal characteristics and crystallization behavior of zinc borosilicate glasses containing Nb2O5
Abstract
<p>Glasses based on the molar composition 60ZnO·(40-x)B<sub>2</sub>O<sub>3</sub>·xSiO<sub>2</sub>, x = 10 or 20, with small additions of Nb<sub>2</sub>O<sub>5</sub> (2.5, 5, 7.5 and 10 mol%), were prepared by melt-quenching. Increasing the Nb<sub>2</sub>O<sub>5</sub> content decreased the glass transition and softening temperatures. Thermal stability increased with Nb<sub>2</sub>O<sub>5</sub> addition and it was higher for glasses based on the composition having the highest SiO<sub>2</sub> content. The thermal expansion coefficient tended to increase with the Nb<sub>2</sub>O<sub>5</sub> amount. Zinc borate and zinc niobate were identified in glasses containing Nb<sub>2</sub>O<sub>5</sub> ≤ 5 mol%, however in glasses based on the highest SiO<sub>2</sub> composition, an additional crystalline phase, willemite, was detected. At the highest Nb<sub>2</sub>O<sub>5</sub> additions, willemite formation was suppressed and zinc niobate plus zinc borate were detected. The non-isothermal crystallization kinetics was investigated, and the effect of Nb<sub>2</sub>O<sub>5</sub> addition and of the base glass composition on the crystallization activation energy and crystallization mechanism was discussed.</p>