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Głuszek, Małgorzata
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Publications (3/3 displayed)
- 2018Enhancement of thermo-rheological properties of smart materials based on SiO2 and PPG modificated with expanded graphitecitations
- 2018Copolymers dispersions designed to shaping of ceramic materials - Investigations of glass transition temperature, thermal stability and decomposition of water-thinnable binderscitations
- 2017New dynamics in poly(propylene glycol) based glass-forming nanocompositescitations
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article
New dynamics in poly(propylene glycol) based glass-forming nanocomposites
Abstract
Results of broadband dielectric spectroscopy and rheological studies of poly(propylene glycol) + SiO2 nanocomposites are presented. They show that the dynamics in high-concentrated composites is dominated by confinement and adsorption effects. The most notable finding is the impact of nanoparticles on fragility, the fractional translational – orientational decoupling and the shift of dynamics towards the pure Vogel-Fulcher-Tammann pattern, associated with the lack of local symmetry preferences.