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Starzonek, S.
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Publications (5/5 displayed)
- 2023Critical Insight into Pretransitional Behavior and Dielectric Tunability of Relaxor Ceramicscitations
- 2020Polyvinylidene difluoride-based composite: glassy dynamics and pretransitional behaviourcitations
- 2019Gelcasting of Al2O3–W composites: Broadband dielectric spectroscopy and rheological studies of tungsten influence on polymerisation kineticscitations
- 2019Multifold pressure-induced increase of electric conductivity in LiFe<inf>0.75</inf>V<inf>0.10</inf>PO<inf>4</inf> glasscitations
- 2017New dynamics in poly(propylene glycol) based glass-forming nanocompositescitations
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article
New dynamics in poly(propylene glycol) based glass-forming nanocomposites
Abstract
Results of broadband dielectric spectroscopy and rheological studies of poly(propylene glycol) + SiO2 nanocomposites are presented. They show that the dynamics in high-concentrated composites is dominated by confinement and adsorption effects. The most notable finding is the impact of nanoparticles on fragility, the fractional translational – orientational decoupling and the shift of dynamics towards the pure Vogel-Fulcher-Tammann pattern, associated with the lack of local symmetry preferences.