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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Lima, Maria Margarida Rolim Augusto
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (17/17 displayed)
- 2018Thermal characteristics and crystallization behavior of zinc borosilicate glasses containing Nb2O5citations
- 2016Formation and crystallization of zinc borosilicate glassescitations
- 2015Crystallization of lithium disilicate-based multicomponent glasses - effect of silica/lithia ratiocitations
- 2014Crystallization kinetics of a barium-zinc borosilicate glass by a non-isothermal methodcitations
- 2014Phase transformation and microstructural evolution after heat treatment of a terbium-doped lithium–aluminum phosphate glasscitations
- 2014Synthesis of Niobium Doped Zinc Borosilicate Glass-ceramics
- 2014Crystallization and microstructure of Eu3+-doped lithium aluminophosphate glasscitations
- 2014Glass transition and crystallization kinetics of a barium borosilicate glass by a non-isothermal methodcitations
- 2014A novel dental restorative glass-ceramic based on fluorcanasite
- 2013Rare-earth doped phosphate glasses
- 2013Crystallization kinetics terbium-doped aluminophosphate glass studied by DSC, XRD and SEM
- 2013Effect of Phosphogypsum on the Clinkerization Temperature of Portland Cement Clinkercitations
- 2012Sintering,Crystallization and Dielectric Behavior of Barium Zinc Borosilicate Glasses - Effect of Barium Oxide substitution for Zinc Oxidecitations
- 2012Structural, electrical and thermal properties of borosilicate glass-alumina compositescitations
- 2008Mechanical characteristics of clay structural ceramics containing coal fly ashcitations
- 2004Recycling of coal fly ash by ceramic processing
- 2000Pressureless sintering of alumina-glass compositescitations
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article
Crystallization and microstructure of Eu3+-doped lithium aluminophosphate glass
Abstract
A transparent Eu3+-doped lithium aluminophosphate glass was prepared by melt-quenching technique. The thermal behavior of the glass was investigated by differential thermal analysis (DTA), the structure was studied by X-ray diffraction (XRD) and the morphology was observed by optical polarization microscopy and scanning electron microscopy (SEM). The activation energy of glass transition and the activation energy of crystallization and Avrami exponent have been evaluated under non-isothermal conditions from the data obtained by DTA at different heating rates. DTA curves exhibited an endothermic peak associated with the glass transition and two exothermic peaks. The mean value calculated for the activation energy of glass transition was 545 kJ mol−1. The activation energy of crystallization was ~400 kJ mol−1 for the first exothermic peak and ~170 kJ mol−1 for the second peak. The Avrami exponent was ~1 for both peaks indicating surface crystallization. XRD results showed that the main crystalline phase, aluminum metaphosphate, Al(PO3)3, and aluminum phosphate, AlPO4, were formed together with lithiumbariumphosphate, Li3Ba(PO3)7, during the first exothermic peak and together with bariumpyrophosphate, Ba2P2O7, during the second peak.Morphological study of heat-treated glass samples revealed microstructural features that confirmed a surface crystallization process.