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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Woźniak-Braszak, Aneta
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (4/4 displayed)
- 2015Characterization of poly(ethylene 2,6-naphthalate)/polycarbonate blends by DSC, NMR off-resonance and DMTA methodscitations
- 2011Molecular dynamics of poly(ethylene terephthalate)/poly(phenylene sulfide) nanocomposites with barium titanatecitations
- 2011Solid state <sup>1</sup>H NMR study of molecular dynamics and domain sizes in PBT with the fullerene derivates: Decylamine-C<inf>60</inf> and tetracyanoethylene oxide-C<inf>60</inf>citations
- 2010Investigation of molecular reorientation in poly(butylene terephthalate)/decylamine/fullerene nanocompositescitations
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article
Solid state <sup>1</sup>H NMR study of molecular dynamics and domain sizes in PBT with the fullerene derivates: Decylamine-C<inf>60</inf> and tetracyanoethylene oxide-C<inf>60</inf>
Abstract
<p>The solid-state <sup>1</sup>H NMR on-resonance and off-resonance techniques have been performed to study molecular dynamics and domain sizes in heterogenous nanocomposites based on poly(butylene terephthalate) and nanoparticles C<sub>60</sub> modified by n-decylamine (DA) or tetracyanoethylene oxide (TCNEO), respectively. The spin-lattice off-resonance relaxation times in the rotating frame T<sub>1ρ</sub><sup>off</sup> as well as the second moment M<sub>2</sub> of the absorption line were analysed as a function of temperature. To determine the size of heterogeneities and characterize the morphology of the nanocomposites, the <sup>1</sup>H NMR spin-diffusion experiment designed by Goldman-Shen [1,2] was performed. The results from the measurements allow us to investigate the spin-diffusion phenomenon and relaxation behavior of the new nanocomposites. © 2010 Elsevier B.V. All rights reserved.</p>