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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Lammertink, Rob
University of Twente
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (21/21 displayed)
- 2024Streamer formation dynamics with mixed bacterial species: effects of cultivation conditions, hydrodynamics, and speciescitations
- 2024Mismatch and mix
- 2022Comparative assessment of hydrocarbon separation performance of bulky poly(urethane-urea)s toward rubbery membranescitations
- 2020Elucidating the effect of chain extenders substituted by aliphatic side chains on morphology and gas separation of polyurethanescitations
- 2019Association of hard segments in gas separation through polyurethane membranes with aromatic bulky chain extenderscitations
- 2017Fabrication of nanoporous graphene/polymer composite membranescitations
- 2015Controlled formation of anatase and rutile TiO2 thin films by reactive magnetron sputteringcitations
- 2015Intrinsic Photocatalytic Assessment of Reactively Sputtered TiO2 Filmscitations
- 2011Hollow fiber ultrafiltration membranes with microstructured inner skincitations
- 2011Carbon nanofibers in catalytic membrane microreactorscitations
- 2010Microstructured hollow fibers for ultrafiltrationcitations
- 2010Shrinkage effects during polmer phase separation on microfabricated moldscitations
- 2010Surface texturing inside ceramic macro/micro channelscitations
- 2010Polymeric microsieves via phase separation microfabricationcitations
- 2009Microcontact Printing of Dendrimers, Proteins, and Nanoparticles by Porous Stampscitations
- 2009Micropatterned polymer films by vapor-induced phase separation using permeable moldscitations
- 2007Morphology and Microtopology of Cation-Exchange Polymers and the Origin of the Overlimiting Currentcitations
- 2006Polymeric microsieves produced by phase separation micromoldingcitations
- 2006Superhydrophobic Surfaces Having Two-Fold Adjustable Roughness Prepared in a Single Stepcitations
- 2005New replication technique for the fabrication of thin polymeric microfluidic devices with tunable porositycitations
- 2005Electrochemistry of Surface-Grafted Stimulus-Responsive Monolayers of Poly(ferrocenyldimethylsilane) on Goldcitations
Places of action
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article
Comparative assessment of hydrocarbon separation performance of bulky poly(urethane-urea)s toward rubbery membranes
Abstract
<p>In the present study, two seriess of poly (urethane urea)s (PUUs) membranes containing aromatic and aliphatic side chains with different sizes were used for separation of higher hydrocarbons from methane. Fourier-transform infrared spectroscopy (FTIR), differential scanning calorimetery (DSC), fractional free volume (FFV) estimation, and gas permeation measurements (CH<sub>4</sub>, C<sub>2</sub>H<sub>6</sub>, C<sub>3</sub>H<sub>8</sub>) were done to characterize the membranes. Bulkier or longer side chains in aromatic and aliphatic substituted PUUs provided enhanced phase separation, lower glass transition temperature and higher gas permeability. Fractional free volume (FFV) as a significant factor controlling gas separation had a reverse trend in both series by increasing the size of side chains. The main findings confirmed the capability of higher phase separated PUUs for hydrocarbon separation. The highest permeability and selectivity was obtained by the longest side chain based PUU with propane permeability of 186 barrer and propane/methane selectivity of 6.51.</p>