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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Yin, C-Y
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Topics
Publications (10/10 displayed)
- 2021Very-few-layer graphene obtained from facile two-step shear exfoliation in aqueous solutioncitations
- 2020Sol-gel derived ITO-based bi-layer and tri-layer thin film coatings for organic solar cells applicationscitations
- 2018Structural, morphological, and optical characterizations of Mo, CrN and Mo:CrN sputtered coatings for potential solar selective applicationscitations
- 2017Improving the optoelectronic properties of titanium-doped indium tin oxide thin filmscitations
- 2017Electrodeposition of polypyrrole and reduced graphene oxide onto carbon bundle fibre as electrode for supercapacitorcitations
- 2017Probing the effects of thermal treatment on the electronic structure and mechanical properties of Ti-doped ITO thin filmscitations
- 2016Structural thermal stability of graphene oxide-doped copper-cobalt oxide coatings as a solar selective surfacecitations
- 2016Effects of annealing temperatures on the morphological, mechanical, surface chemical bonding, and solar selectivity properties of sputtered TiAlSiN thin filmscitations
- 2016Structural, optical, and mechanical properties of cobalt copper oxide coatings synthesized from low concentrations of sol-gel processcitations
- 2014Understanding local bonding structures of Ni-doped chromium nitride coatings through synchrotron radiation NEXAFS spectroscopycitations
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article
Structural thermal stability of graphene oxide-doped copper-cobalt oxide coatings as a solar selective surface
Abstract
3d transition metal oxides based thin film coatings such as copper-cobalt oxides exhibit high absorption in the visible region and low emittance in the infra-red to far-infra-red region of the solar spectrum which is favourable for use as potential selective surface materials in photothermal devices. These materials have the potential to minimize heating while increasing absorption in the operative spectrum range and therefore achieve higher solar selectivity. A series of mixed copper-cobalt metal spinel oxides (CuxCoyOz) doped with graphene oxide thin films were deposited on commercial grade aluminium substrates using a sol–gel dip-coating technique at an annealing temperature of 500 °C in air for 1 h. Characterizations of the synthesized films were carried out by high temperature synchrotron radiation X-ray Diffraction (SR-XRD), UV-Vis, Fourier Transform infrared spectroscopy (FTIR) and X-ray photoelectron microscopy (XPS) techniques. High thermal stability of coatings with multiple phases, binary and ternary metal oxides, was defined through SR-XRD study. FTIR analysis shows moderate (<80%) to high (up to 99%) reflectance in the infra-red region while the UV-Vis investigations demonstrate that, in the visible region, solar absorption increases gradually (up to 95%) with the addition of graphene oxide to the CuxCoyOz coatings. With the incorporation of 1.5 wt% of graphene oxide to the copper-cobalt oxide coatings, a high solar selectivity of 29.01 (the ratio of the average solar absorptance in visible and the average thermal emittance in infra-red to far infra-red region; α/ε) was achieved.