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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Gorr, Bronislava
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (17/17 displayed)
- 2024The effect of Ni additions on the oxidation behaviour of Co–Re–Cr high-temperature alloyscitations
- 2023Lanthanum plumbide as a new neutron multiplier material
- 2023Formation and thermal stability of two-phase microstructures in Al-containing refractory compositionally complex alloys
- 2023Thermo-mechanische Modellierung interpenetrierender Metall-Keramik Verbundwerkstoffe auf Basis hochhomogener Schaumstrukturen
- 2022Formation and thermal stability of two-phase microstructures in Al-containing refractory compositionally complex alloyscitations
- 2022Pesting Resistance in High Mo Containing Alloys
- 2022Characterization of the Isothermal and Thermomechanical Fatigue Behavior of a Duplex Steel Considering the Alloy Microstructure
- 2022Interface reactions of magnetron sputtered Si-based dual layer coating systems as oxidation protection for Mo-Si-Ti alloyscitations
- 2021Current Status of Research on the Oxidation Behavior of Refractory High Entropy Alloyscitations
- 2020Controlling crystallographic ordering in Mo–Cr–Ti–Al high entropy alloys to enhance ductilitycitations
- 2020On the chemical and microstructural requirements for the pesting-resistance of Mo-Si-Ti alloyscitations
- 2020Formation of complex intermetallic phases in novel refractory high-entropy alloys NbMoCrTiAl and TaMoCrTiAl: Thermodynamic assessment and experimental validationcitations
- 2019On the oxidation mechanism of refractory high entropy alloyscitations
- 2019Constitution, oxidation and creep of eutectic and eutectoid Mo-Si-Ti alloyscitations
- 2017Oxidationsverhalten refraktärmetallbasierter Konstruktionswerkstoffe für Hochtemperaturanwendungen ; Oxidation behavior of high temperature refractory metal-based structural materials
- 2017Effect of microalloying with silicon on high temperature oxidation resistance of novel refractory high-entropy alloy Ta-Mo-Cr-Ti-Al
- 2017Combinatorial exploration of the high entropy alloy system Co-Cr-Fe-Mn-Nicitations
Places of action
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article
On the chemical and microstructural requirements for the pesting-resistance of Mo-Si-Ti alloys
Abstract
In recent publications [Schliephake et al. in Intermetallics 104 (2019) 133-142 and Obert, Kauffmann & Heilmaier in Acta Materialia, 184 (2020) 132-142], an unexpected pesting-stability of fully eutectic and specific eutectic-eutectoid Mo-Si-Ti alloys was found. Several potential reasons were proposed: microstructural length scale being typically very fine due to the eutectic and eutectoid reactions, the phase distribution including the fraction of the eutectic and eutectoid regions, as well as the chemical composition of the individual phases. In the present study, we prove the Ti content to be decisive for the pesting-resistance in air at 800 °C by investigating the microstructure and oxidation behaviour of Mo-Si-Ti alloys with systematically varying nominal Ti content. A critical Ti content of 43 at% was identified. Due to the phase equilibrium, this corresponds to a local Ti content in Mo solid solution of 35 at%. Other microstructural properties such as (i) lamellar size within eutectic and eutectoid regions and (ii) volume fraction of the eutectic and eutectoid regions were demonstrated to have an insignificant influence on the pesting-resistance of the alloys. Rather, the assessment of the oxidation behaviour of the monolithic phase MoSS, which was identified to be crucial for the oxidation behaviour of the Mo-Si-Ti alloys, confirmed an improvement in oxidation behaviour with increasing Ti content.