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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Obot, Ime B.
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (10/10 displayed)
- 2022Corrosion Inhibition of Rumex vesicarius Mediated Chitosan-AgNPs Composite for C1018 CS in CO2-Saturated 3.5% NaCl Medium under Static and Hydrodynamic Conditionscitations
- 2022Elucidation of corrosion inhibition property of compounds isolated from Butanolic Date Palm Leaves extract for low carbon steel in 15% HCl solutioncitations
- 2021Date palm leaves extract as a green and sustainable corrosion inhibitor for low carbon steel in 15 wt.% HCl solutioncitations
- 2021Effect of intensifier additives on the performance of butanolic extract of date palm leaves against the corrosion of api 5l x60 carbon steel in 15 wt.% hcl solutioncitations
- 2020Preparation of silver/chitosan nanofluids using selected plant extractscitations
- 2020Exploration of natural polymers for use as green corrosion inhibitors for AZ31 magnesium alloy in saline environmentcitations
- 2020Corrosion inhibition effect of a benzimidazole derivative on heat exchanger tubing materials during acid cleaning of multistage flash desalination plantscitations
- 2019Studies of the anticorrosion property of a newly synthesized Green isoxazolidine for API 5L X60 steel in acid environmentcitations
- 2018Comparative studies on the corrosion inhibition efficacy of ethanolic extracts of date palm leaves and seeds on carbon steel corrosion in 15% HCl solutioncitations
- 2018Exploration of Dextran for Application as Corrosion Inhibitor for Steel in Strong Acid Environmentcitations
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article
Studies of the anticorrosion property of a newly synthesized Green isoxazolidine for API 5L X60 steel in acid environment
Abstract
<p>The potential of an environmentally friendly novel synthesized and characterized isoxazolidine derivative namely 5-(4-dodecyloxy-3-methoxybenzyl)-2-methylisoxazolidine (DMBMI) as anticorrosion agent for carbon steel in 1»mol/L HCl solution was investigated using gravimetric and electrochemical techniques. Kinetics parameters of the corrosion process and the thermodynamic data of adsorption of the organic molecule on the carbon steel surface was also assessed in order to characterize the performance of the studied compound as a corrosion inhibitor. The solubility, toxicity and the state of the molecule at the acidic pH (1»mol/L HCl) was predicted. It was found that the synthesized compound is green (environmentally friendly) with an optimum solubility of 23.8»mg/L. Also the molecule exists 100 percent in protonated form in 1»mol/L HCl (pH»=»0). The molecule possesses anticorrosion property against steel corrosion in acid environment. Corrosion retardation efficacy is dependent on concentration and temperature. DMBMI exhibited concentration dependent corrosion inhibition ability influencing mainly anodic metal dissolution based on potentiodynamic polarization data. Addition of KI through the mechanism of competitive adsorption enhanced the inhibition efficiency considerably. The active sites for the interaction of DMBMI with steel surface was calculated using quantum chemical method while the adsorption energy between the inhibitor and steel surface was derived via Monte Carlo simulations. Results from theoretical studies and surface analysis are in conformity and reveal that the O and N heteroatoms in the synthesized molecule are the interaction centers.</p>