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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Walton, Allan
University of Birmingham
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (17/17 displayed)
- 2024Development of anisotropic Nd-Fe-B powder from isotropic gas atomized powdercitations
- 2022Limitations in the grain boundary processing of the recycled HDDR Nd-Fe-B systemcitations
- 2020Limitations in grain boundary processing of the recycled HDDR Nd-Fe-B systemcitations
- 2020Recycling of bonded NdFeB permanent magnets using ionic liquidscitations
- 2020The extraction of NdFeB magnets from automotive scrap rotors using hydrogencitations
- 2019Coercivity increase of the recycled HDDR Nd-Fe-B powders doped with DyF3 and processed via Spark Plasma Sintering & the effect of thermal treatmentscitations
- 2017Isotropic NdFeB hard magnets
- 2017Metal Injection Moulding for the Production of Recycled Rare Earth Magnets
- 2016REE Recovery from End-of-Life NdFeB Permanent Magnet Scrap: A Critical Reviewcitations
- 2016The Hydrogen Ductilisation Process (HyDP) for shaping NdFeB magnetscitations
- 2016Metal Injection Moulding of NdFeB Based on Recycled Powders
- 2016Metal Injection Moulding of NdFeB based on Recycled Powders
- 2016The development of microstructure during hydrogenation–disproportionation–desorption–recombination treatment of sintered neodymium-iron-boron-type magnetscitations
- 2016Novel "Flash Spark Plasma Sintering" method for the rapid fabrication of nanostructured and anisotropic rare-earth lean permanent magnetic materials
- 2014The Effect of Ni Impurities on HDDR Processing of Scrap Sintered NdFeB Magnets
- 2003Hydrogenation properties of nanocrystalline Mg- and Mg₂Ni-based compounds modified with platinum group metals (PGMs)
- 2002Low temperature hydrogenation properties of platinum group metal treated, nickel metal hydride electrode alloycitations
Places of action
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article
The development of microstructure during hydrogenation–disproportionation–desorption–recombination treatment of sintered neodymium-iron-boron-type magnets
Abstract
The hydrogen absorption and desorption characteristics of the hydrogenation disproportionation desorption and recombination (HDDR) process on scrap sintered neodymium-iron-boron (NdFeB) type magnets have been investigated. At each stage of the process, the microstructural changes have been studied using high resolution scanning electron microscopy. It was found that the disproportionation reaction initiates at grain boundaries and triple points and then propagates towards the centre of the matrix grains. This process was accelerated at particle surfaces and at free surfaces produced by any cracks in the powder particles. However, the recombination reaction appeared to initiate randomly throughout the particles with no apparent preference for particle surfaces or internal cracks. During the hydrogenation of the grain boundaries and triple junctions, the disproportionation reaction was, however, affected by the much higher oxygen content of the sintered NdFeB compared with that of the as-cast NdFeB alloys. Throughout the entire HDDR reaction the oxidised triple junctions (from the sintered structure) remained unreacted and hence, remained in their original form in the fine recombined microstructure. This resulted in a very significant reduction in the proportion of cavitation in the final microstructure and this could lend to improved consolidation in the recycled magnets.