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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Felton, Solveig
Queen's University Belfast
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (14/14 displayed)
- 2022Thermal and magnetic field switching in a two-step hysteretic MnIII spin crossover compound coupled to symmetry breakingscitations
- 2022Thermal and Magnetic Field Switching in a Two‐Step Hysteretic Mn<sup>III</sup> Spin Crossover Compound Coupled to Symmetry Breakingscitations
- 2022Thermal and Magnetic Field Switching in a Two‐Step Hysteretic Mn(III) Spin Crossover Compound Coupled to Symmetry Breakingscitations
- 2022Thermal and magnetic field switching in a two-step hysteretic Mn III spin crossover compound coupled to symmetry breakingscitations
- 2021Percolation in metal-insulator composites of randomly packed spherocylindrical nanoparticlescitations
- 2019Controlling Ferromagnetic Ground States and Solitons in Thin Films and Nanowires Built from Iron Phthalocyanine Chainscitations
- 2016Evaluation of La1−xSrxMnO3 (0 ≤ x < 0.4) synthesised via a modified sol–gel method as mediators for magnetic fluid hyperthermiacitations
- 2006Simulations of magnetic microstructure in thin film elements used for programmable motion of magnetic particlescitations
- 2006Chemical tuning of the interlayer magnetic coupling in TlCo2Se2-xSxcitations
- 2005Cycloidal magnetic order in the compound IrMnSicitations
- 2005Magnetic short-range order in the new ternary phase Mn8Pd15Si7citations
- 2004Magnetic and electronic structure of TICo2S2citations
- 2004Crystal and magnetic structure of Mn3IrSicitations
- 2001Fragility of the spin-glass-like collective state to a magnetic field in an interacting Fe-C nanoparticle systemcitations
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article
Chemical tuning of the interlayer magnetic coupling in TlCo2Se2-xSx
Abstract
The system TlCo2Se2-xSx has been thoroughly investigated by neutron powder diffraction and SQUID magnetometry. TlCo2Se2-xSx is a layered tetragonal structure containing atomic cobalt layers separated by a distance of 6.4 angstrom in the sulphide and 6.8 angstrom in the selenide. The solid solubility of isovalent selenium and sulphur atoms in the structure makes it possible to continuously vary the interlayer distance and thereby tune the magnetic coupling between the Co-layers. At low temperatures, the Co-atoms are ferromagnetically ordered within the layers and magnetic moments lie in the ab-plane. However, these Co-moments form a helical magnetic structure that prevails for 0 <= x <= 1.5 with a gradual decrease of the angle between adjacent Co-layers from 122 degrees to 39 degrees. For x >= 1.75, a collinear ferromagnetic structure is stable. The relationship between the coupling angle and the Co-interlayer separation shows an almost linear behaviour. The helical phase contains no net spontaneous magnetic moment up to TlCo2SeS, where a small net magnetic moment appears that increases until the ferromagnetic structure is found for 1.75 <= x <= 2.0. (C) 2005 Elsevier B.V. All rights reserved.