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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Kontonasaki, Eleana
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (6/6 displayed)
- 2023Zirconia Nanoparticles as Reinforcing Agents for Contemporary Dental Luting Cements: Physicochemical Properties and Shear Bond Strength to Monolithic Zirconiacitations
- 2022Poly(Glycerol Succinate) as Coating Material for 1393 Bioactive Glass Porous Scaffolds for Tissue Engineering Applicationscitations
- 2021Sol–Gel Synthesis and Characterization of YSZ Nanofillers for Dental Cements at Different Temperaturescitations
- 2021Synthesis and Characterization of Mesoporous Mg- and Sr-Doped Nanoparticles for Moxifloxacin Drug Delivery in Promising Tissue Engineering Applicationscitations
- 2020Mechanical and thermal properties of PMMA resin composites for interim fixed prostheses reinforced with calcium β-pyrophosphatecitations
- 2019Polyglycerol Hyperbranched Polyesters: Synthesis, Properties and Pharmaceutical and Biomedical Applicationscitations
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article
Mechanical and thermal properties of PMMA resin composites for interim fixed prostheses reinforced with calcium β-pyrophosphate
Abstract
Interim restorations are essential in fixed prosthodontics as they provide temporary protection of teeth before the insertion of the permanent restoration. Poly(methyl methacrylate) (PMMA) is widely used in the fabrication of interim-fixed restorations as it is a biocompatible material with a lot of convenient properties. However, it exhibits low impact and tensile strength and therefore it is necessary to be reinforced. Calcium β-pyrophosphate (β-CPP) is considered a promising reinforcing material for dental applications, especially for enamel regeneration due to its stability at low pH and its low wear rate. The aim of this study was to manufacture PMMA/β-CPP composites suitable for fixed-interim restorations and to study their mechanical and thermal properties. In order to enhance β-CPP dispersion into PMMA matrix, ball-milling was performed for 1 or 6 h. Three-point bending test was performed to study flexural strength, Dynamic Mechanical Analysis (DMA) to reveal the elastic and viscous moduli along with T g , Fourier Transform Infrared Spectroscopy (FTIR) and X-Ray Diffraction Analysis (XRD) to investigate the structure of the materials and SEM for the morphological evaluation of both composite powders and polymerized specimens. Thermogravimetric Analysis (TGA) and Differential Scanning Calorimetry (DSC) experiments were performed to study their thermal properties. A statistically significant increase in flexural strength was found in the 0.5, 0.75 and 1% composite groups after 6 h ball-milling, relative to the control, with the 6 h ball milling mixed specimens, presenting the highest flexural strength values. The brittle fracture type was common to all groups. An obvious improvement of the mechanical properties and a slight improvement in the thermal stability of the composite materials values were also observed as β-CPP content was increased, while T g values were statistically not-affected.