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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Kraus, Florian
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (18/18 displayed)
- 2024[Br4F21]− - a unique molecular tetrahedral interhalogen ion containing a μ4-bridging fluorine atom surrounded by BrF5 moleculescitations
- 2022Photochemistry with ClF3 – An Access to [ClOF2]+ Saltscitations
- 2022Bromine Pentafluoride BrF5, the Formation of [BrF6]− Salts, and the Stereochemical (In)activity of the Bromine Lone Pairscitations
- 2021DFT-Guided Crystal Structure Redetermination and Lattice Dynamics of the Intermetallic Actinoid Compound UIrcitations
- 2021Barium bis[tetrafluoridobromate(III)]citations
- 2021Coordination of trivalent lanthanum and cerium, and tetravalent cerium and actinides (An = Th(iv), U(iv), Np(iv)) by a 4-phosphoryl 1H-pyrazol-5-olate ligand in solution and the solid statecitations
- 2021Photochemistry with Chlorine Trifluoride : Syntheses and Characterization of Difluorooxychloronium(V) Hexafluorido(non)metallates(V), [ClOF2][MF6] (M=V, Nb, Ta, Ru, Os, Ir, P, Sb)citations
- 2020Redetermination of the crystal structure of caesium tetrafluoridobromate(III) from single-crystal X-ray diffraction datacitations
- 2020Reactions in Anhydrous Liquid Ammonia : Syntheses and Crystal Structures of [M(NH3)8]I2 (M = Eu, Yb) with Bicapped Trigonal-Prismatic Octaammine Lanthanoid(II) Cations
- 2019Evolutionary Algorithm-Based Crystal Structure Prediction for Copper (I) Fluoridecitations
- 2019Rubidium tetrafluoridobromate(III): redetermination of the crystal structure from single-crystal X-ray diffraction datacitations
- 2019Crystal Structures of α- And β-Nitrogen Trifluoridecitations
- 2019Half-metallicity in uranium intermetallicscitations
- 2019Synthesis and Characterization of [Br 3 ][MF 6 ] (M=Sb, Ir), as well as Quantum Chemical Study of [Br 3 ] + citations
- 2019Reactions of KBrF4 with platinum metalscitations
- 2018Redetermination of the crystal structure of K[BrF4] from single-crystal X-ray diffraction datacitations
- 2012Uranyl Halides from Liquid Ammoniacitations
- 2011The Complex Amide K-2[Zr(NH2)(6)]citations
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article
Reactions of KBrF4 with platinum metals
Abstract
<p>The reaction of various platinum metals (M = Ru, Os, Rh, Ir, Pd, Pt) with KBrF<sub>4</sub> was investigated upon heating their mixtures to 400 °C. The formation of potassium fluorido platinum metallates in oxidation states +4 or +5, K<sub>2</sub>MF<sub>6</sub> or KMF<sub>6</sub>, respectively, was observed in all cases. The obtained products were tested for their stability in water. Depending on the platinum metal, they were either stable, were reduced to the oxidation state +4, or were hydrolyzed to so far unidentified phases. K<sub>2</sub>RuF<sub>6</sub>, K<sub>2</sub>OsF<sub>6</sub>, α-K<sub>2</sub>PdF<sub>6</sub>, β-K<sub>2</sub>PdF<sub>6</sub>, which were previously only poorly characterized, were structurally reinvestigated by single crystal or powder X-ray diffraction, Raman and IR spectroscopy. The three former compounds crystallize isotypic in the trigonal, the latter in the hexagonal crystal system. The α→β phase transition of K<sub>2</sub>PdF<sub>6</sub> was found to be reconstructive. Quantum chemical calculations were used to investigate the crystal structures.</p>