| People | Locations | Statistics |
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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Wiecinska, Paulina
Warsaw University of Technology
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (5/5 displayed)
- 2024Functionalization of graphene oxide surface by conjugation with glucosamine and analysis of interactions occurring in nanoceramic-graphene heterostructurescitations
- 2023Coordination complexes as substitutes for metallic powders in ceramic-matrix-composites manufactured by aqueous colloidal processing: Enhanced fracture toughness and quantitative microstructure analysiscitations
- 2022Graphene-reinforced ceramics obtained by slip casting and pressureless sintering: Interactions and stability of particles in aqueous environmentcitations
- 2021The influence of the chemical structure of selected polymers on the properties of ferroelectric ceramic-polymer compositescitations
- 2015Organic additives in gel-tape casting of ceramic powders – a novel approach to the problem of elasticity and cracking of thin tapescitations
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article
Coordination complexes as substitutes for metallic powders in ceramic-matrix-composites manufactured by aqueous colloidal processing: Enhanced fracture toughness and quantitative microstructure analysis
Abstract
In fabrication of metal-reinforced ceramics, metallic powders are used as one of the raw materials, however, they hinder obtaining nanometallic particles in the matrix. The use of metallic nanopowders is inefficient, because they are highly flammable and require special storage and handling conditions (cool, dry inert gas, tightly sealed). Replacing metallic powders with coordination complexes allows to obtain nanocomposites in harmless manufacturing processes. The use of coordination complex of molybdenum (molybdenyl acetylacetonate) allowed to fabricate ZrO2/Mo composites by slip casting and gelcasting. The increase in fracture toughness (ca. 25%) was observed with the little concentration of the metallic phase (up to 1.5 wt%) in a composite. It results from gaining fine metallic particles (ca. 62 nm) in the ceramic matrix. SEM analysis revealed that crack propagation is inhibited by nano-sized metallic particles according to three mechanisms: crack deflection, crack blocking by plastic deformation and interface debonding.