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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Somers, Nicolas
University of Liège
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (15/15 displayed)
- 2024Rapid, Direct Fabrication of Thermochromic Ceramic Composite Sensors via Flash Lamp Annealing
- 2024Infrared irradiation to drive phosphate condensation as a route to direct additive manufacturing of oxide ceramicscitations
- 2023Mg2+, Sr2+, Ag+, and Cu2+ co‐doped β‐tricalcium phosphate: Improved thermal stability and mechanical and biological propertiescitations
- 2023Fabrication of doped β-tricalcium phosphate bioceramics by Direct Ink Writing for bone repair applicationscitations
- 2023Infrared Irradiation to Drive Phosphate Condensation as a Route to Direct Additive Manufacturing of Oxide Ceramicscitations
- 2023Synthesis and Direct Ink Writing of doped β-tricalcium phosphate bioceramics for bone repair applications
- 20233D printing of doped β-tricalcium phosphate bioceramics using robocasting
- 2022Fabrication of doped β-tricalcium phosphate bioceramics by Direct Ink Writing for bone repair applicationscitations
- 2022Young Ceramists in the Spotlight
- 2022Fabrication of doped b-tricalcium phosphate bioceramics by robocasting for bone repair applications
- 2022Fabrication of doped b-tricalcium phosphate bioceramics by robocasting for bone repair applications
- 2021Fabrication of higher thermal stability doped β-tricalcium phosphate bioceramics by robocasting
- 2021Influence of dopants on thermal stability and densification of β-tricalcium phosphate powderscitations
- 2021Development of calcium phosphate suspensions suitable for the stereolithography processcitations
- 2020Fabrication of higher thermal stability doped β-tricalcium phosphate bioceramics by robocasting
Places of action
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article
Fabrication of doped β-tricalcium phosphate bioceramics by Direct Ink Writing for bone repair applications
Abstract
β-tricalcium phosphate (β-TCP, β-Ca3(PO4)2) is one of the most attractive biomaterials for bone regeneration and β-TCP macroporous scaffolds are very promising for both cell proliferation and mechanical support. The Additive Manufacturing (AM) process called Direct Ink Writing (DIW), based on the extrusion of a concentrated ceramic slurry, is particularly adapted to resolve the main drawbacks associated with conventional shaping of ceramic scaffolds. In this work, co-doped β-TCP powders were synthetized and used to print macroporous scaffolds by DIW. Doped β-TCP powders have been proved to exhibit higher thermal stability, densification and mechanical properties compared to undoped β-TCP. Two co-doped compositions were produced via the aqueous precipitation technique combining magnesium, strontium, silver and copper cations: Mg-Sr (2.0–2.0 mol%) and Mg-Sr-Ag-Cu (2.0–2.0–0.1–0.1 mol%). DIW slurries were optimized with undoped and co-doped β-TCP with the use of a dispersant and a carboxymethylcellulose and polyethyleneimine mixture to obtain aqueous slurries filled with 42 vol% of powder. Complete rheological characterizations were realized to assess the suitability of the β-TCP slurries for the DIW process (shear-thinning and thixotropic behaviour). The whole processing chain including printing, osmotic drying (PEG 10000) and sintering (1100 °C, 3 h) was optimized to successfully print co-doped β-TCP macroporous scaffolds. Characterizations after sintering showed a reduction of macropores and microcracks using co-doped β-TCP powders as well as improved compressive strengths and densities compared to undoped β-TCP. A significant enhancement of compressive strength values was obtained compared to literature data.