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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Giuntini, Diletta
Hamburg University of Technology
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (25/25 displayed)
- 2023Efficient modelling of ceramic sintering processes:Application to bilayers and membranescitations
- 2023Nanoindentation creep of supercrystalline nanocompositescitations
- 2023Efficient modelling of ceramic sintering processescitations
- 2022Nanoindentation creep of supercrystalline nanocomposites
- 2022Nanoindentation of Supercrystalline Nanocomposites:Linear Relationship Between Elastic Modulus and Hardnesscitations
- 2022Strengthening Engineered Nanocrystal Three-Dimensional Superlattices via Ligand Conformation and Reactivitycitations
- 2022Bridging Nanocrystals to Robust, Multifunctional, Bulk Materials through Nature-Inspired, Hierarchical Designcitations
- 2022Nanoindentation of Supercrystalline Nanocompositescitations
- 2021Constitutive and fracture behavior of ultra-strong supercrystalline nanocompositescitations
- 2021Defects and plasticity in ultrastrong supercrystalline nanocompositescitations
- 2021Deformation Behavior of Cross-Linked Supercrystalline Nanocomposites: An in Situ SAXS/WAXS Study during Uniaxial Compressioncitations
- 2021Deformation Behavior of Cross-Linked Supercrystalline Nanocompositescitations
- 2020Ultra-thin and ultra-strong organic interphase in nanocomposites with supercrystalline particle arrangement: Mechanical behavior identification via multiscale numerical modelingcitations
- 2020Mapping the Mechanical Properties of Hierarchical Supercrystalline Ceramic-Organic Nanocompositescitations
- 2019Hierarchical supercrystalline nanocomposites through the self-assembly of organically-modified ceramic nanoparticlescitations
- 2019Hierarchical supercrystalline nanocomposites through the self-assembly of organically-modified ceramic nanoparticles
- 2019Hierarchical supercrystalline nanocomposites through the self-assembly of organically-modified ceramic nanoparticlescitations
- 2019Nanoindentation-based study of the mechanical behavior of bulk supercrystalline ceramic-organic nanocomposites
- 2019Nanoindentation-based study of the mechanical behavior of bulk supercrystalline ceramic-organic nanocompositescitations
- 2019Iron oxide-based nanostructured ceramics with tailored magnetic and mechanical properties: Development of mechanically robust, bulk superparamagnetic materials
- 2019Anisotropy of mass transfer during sintering of powder materials with pore–particle structure orientationcitations
- 2019Iron oxide-based nanostructured ceramics with tailored magnetic and mechanical properties: development of mechanically robust, bulk superparamagnetic materialscitations
- 2019Modulating the Mechanical Properties of Supercrystalline Nanocomposite Materials via Solvent–Ligand Interactionscitations
- 2016Sintering shape distortions controlled by interface roughness in powder compositescitations
- 2013Initial stage of free pressureless spark-plasma sintering of vanadium carbide: Determination of surface diffusion parameterscitations
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article
Nanoindentation-based study of the mechanical behavior of bulk supercrystalline ceramic-organic nanocomposites
Abstract
Bulk poly-supercrystalline ceramic-organic nanocomposites were produced and characterized with a nanoindentation-based study. These nanocomposites were processed using two different routines, to compare their properties with and without crosslinking the organic ligands interfacing the ceramic nanoparticles. Together with the expected material strengthening induced by crosslinking, a distinct response emerges when using Berkovich and cube-corner indenters. The supercrystalline materials are prone to compaction, cracking and chipping phenomena that become more severe when a sharper tip is employed, implying that a Berkovich indenter is more suitable for the evaluation of elastic modulus and hardness. The cube-corner tip, on the other hand, is employed for the investigation of fracture toughness, comparing two methods and multiple models available from the literature. The fracture toughness outcomes suggest that cracks evolve with a quarter-penny shaped profile at the indent’s corners, and that extrinsic toughening mechanisms, such as plastic-like deformation and crack deflection, play a significant role.