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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Ramousse, Severine
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (24/24 displayed)
- 2016Processing and characterization of multilayers for energy device fabrication (invited)
- 2014Densification and grain growth kinetics of Ce 0.9 Gd 0.1 O 1.95 in tape cast layers: The influence of porositycitations
- 2014Thermo-mechanical properties of SOFC components investigated by a combined method
- 2014Densification and grain growth kinetics of Ce0.9Gd0.1O1.95 in tape cast layers: The influence of porositycitations
- 2013Shape distortion and thermo-mechanical properties of dense SOFC components from green tape to sintered body
- 2013Sintering process optimization for multi-layer CGO membranes by in situ techniquescitations
- 2013Camber Evolution and Stress Development of Porous Ceramic Bilayers During Co-Firingcitations
- 2013Camber Evolution and Stress Development of Porous Ceramic Bilayers During Co-Firingcitations
- 2013The effect of forming stresses on the sintering of ultra-fine Ce0.9Gd0.1O2-δ powderscitations
- 2012Shape distortion and thermo-mechanical properties of SOFC components from green tape to sintering body
- 2012Shape distortion and thermo-mechanical properties of SOFC components from green tape to sintering body
- 2012Analysis of the sintering stresses and shape distortion produced in co-firing of CGO-LSM/CGO bi-layer porous structures
- 2012Analysis of the sintering stresses and shape distortion produced in co-firing of CGO-LSM/CGO bi-layer porous structures
- 2012Characterization of impregnated GDC nano structures and their functionality in LSM based cathodescitations
- 2011Manufacturing and characterization of metal-supported solid oxide fuel cellscitations
- 2011Manufacturing and characterization of metal-supported solid oxide fuel cellscitations
- 2011Planar metal-supported SOFC with novel cermet anodecitations
- 2011Planar metal-supported SOFC with novel cermet anodecitations
- 2009Status of Development and Manufacture of Solid Oxide Fuel Cell at Topsoe Fuel Cell A/S and Risø/DTUcitations
- 2009Status of Development and Manufacture of Solid Oxide Fuel Cell at Topsoe Fuel Cell A/S and Risø/DTUcitations
- 2009Development of Planar Metal Supported SOFC with Novel Cermet Anodecitations
- 2009Development of Planar Metal Supported SOFC with Novel Cermet Anodecitations
- 2006Break down of losses in thin electrolyte SOFCscitations
- 2005Nanostructured lanthanum manganate composite cathodecitations
Places of action
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article
Sintering process optimization for multi-layer CGO membranes by in situ techniques
Abstract
The sintering of asymmetric CGO bi-layers (thin dense membrane on a porous support; Ce0.9Gd0.1O1.95-delta = CGO) with Co3O4 as sintering additive has been optimized by combination of two in situ techniques. Optical dilatometry revealed that bi-layer shape and microstructure are dramatically changing in a narrow temperature range of less than 100 degrees C. Below 1030 degrees C, a higher densification rate in the dense membrane layer than in the porous support leads to concave shape, whereas the densification rate of the support is dominant above 1030 degrees C, leading to convex shape. A fiat bi-layer could be prepared at 1030 degrees C, when shrinkage rates were similar. In situ van der Pauw measurements on tape cast layers during sintering allowed following the conductivity during sintering. A strong increase in conductivity and in activation energy E-a for conduction was observed between 900 and 1030 degrees C indicating an activation of the reactive sintering process and phase transformation of cobalt oxide. (C) 2012 Elsevier Ltd. All rights reserved.