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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Foghmoes, Søren Preben Vagn
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (15/15 displayed)
- 2020Surface treatments and functionalization of metal‐ceramic membranes for improved enzyme immobilization performancecitations
- 2018Citrate- and glycerol triesters as novel dual-functional dispersants and plasticisers for ceramic processingcitations
- 2017Development of redox stable, multifunctional substrates for anode supported SOFCS
- 2016Complementary analysis techniques applied on optimizing suspensions of yttria stabilized zirconiacitations
- 2016Design and optimization of porous ceramic supports for asymmetric ceria-based oxygen transport membranescitations
- 2016Design and optimization of porous ceramic supports for asymmetric ceria-based oxygen transport membranescitations
- 2016Novel ceramic processing method for substitution of toxic plasticizerscitations
- 2014Densification and grain growth kinetics of Ce 0.9 Gd 0.1 O 1.95 in tape cast layers: The influence of porositycitations
- 2014In situ characterization of delamination and crack growth of a CGO–LSM multi-layer ceramic sample investigated by X-ray tomographic microscopycitations
- 2014Densification and grain growth kinetics of Ce0.9Gd0.1O1.95 in tape cast layers: The influence of porositycitations
- 2013Sintering process optimization for multi-layer CGO membranes by in situ techniquescitations
- 2013The effect of forming stresses on the sintering of ultra-fine Ce0.9Gd0.1O2-δ powderscitations
- 2012Durable and Robust Solid Oxide Fuel Cells
- 2011Evaluation of thin film ceria membranes for syngas membrane reactors—Preparation, characterization and testingcitations
- 2011On the use of supported ceria membranes for oxyfuel process/syngas productioncitations
Places of action
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article
Sintering process optimization for multi-layer CGO membranes by in situ techniques
Abstract
The sintering of asymmetric CGO bi-layers (thin dense membrane on a porous support; Ce0.9Gd0.1O1.95-delta = CGO) with Co3O4 as sintering additive has been optimized by combination of two in situ techniques. Optical dilatometry revealed that bi-layer shape and microstructure are dramatically changing in a narrow temperature range of less than 100 degrees C. Below 1030 degrees C, a higher densification rate in the dense membrane layer than in the porous support leads to concave shape, whereas the densification rate of the support is dominant above 1030 degrees C, leading to convex shape. A fiat bi-layer could be prepared at 1030 degrees C, when shrinkage rates were similar. In situ van der Pauw measurements on tape cast layers during sintering allowed following the conductivity during sintering. A strong increase in conductivity and in activation energy E-a for conduction was observed between 900 and 1030 degrees C indicating an activation of the reactive sintering process and phase transformation of cobalt oxide. (C) 2012 Elsevier Ltd. All rights reserved.