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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Ficek, Mateusz
Gdańsk University of Technology
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (7/7 displayed)
- 2022The effect of boron concentration on the electrical, morphological and optical properties of boron-doped nanocrystalline diamond sheets: Tuning the diamond-on-graphene vertical junctioncitations
- 2022Tailoring of Optical Properties of Methacrylate Resins Enriched by HPHT Microdiamond Particlescitations
- 2022Volumetric incorporation of NV diamond emitters in nanostructured F2 glass magneto-optical fiber probescitations
- 2020Boron-Doped Nanocrystalline Diamond–Carbon Nanospike Hybrid Electron Emission Sourcecitations
- 2020Electrochemical performance of thin free-standing boron-doped diamond nanosheet electrodescitations
- 2018Preparation and characterization of TiO2/carbon nanowall composite on a transparent substratecitations
- 2016Ellipsometric investigation of nitrogen doped diamond thin films grown in microwave CH4/H-2/N-2 plasma enhanced chemical vapor depositioncitations
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article
Electrochemical performance of thin free-standing boron-doped diamond nanosheet electrodes
Abstract
In the following work we describe preparation and the electrochemical performance of thin and free-standing heavy boron-doped diamond (BDD) nanosheets. The investigated foils were deposited on Ta substrate using microwave plasma-enhanced chemical vapor deposition technique (MPECVD). Foils of two B-dopant densities were investigated, obtained on the base of 10 k and 20 k ppm [B]/[C] ratio in the gas admixture. The obtained foils can be easily peeled from substrate in deionized water to be then attached to other material, in this case polydimethylsiloxane (PDMS). We have shown that the top surface and the bottom side of investigated boron-doped diamond nanosheet possess significantly altered morphology and physico-chemical properties, revealed by electron microscopy, Raman spectroscopy and electrochemistry. The voltammetric response of investigated BDD foils as working electrodes indicates the highest activity for the nanosheet with higher dopant concentration, in particular on its top surface. Furthermore, electrodes are characterized with altered kinetics, characteristic for partially blocked electrodes with quasi-reversible charge transfer.