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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Rong, Yuanyang
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (7/7 displayed)
- 2020Free-Standing Graphene Oxide and Carbon Nanotube Hybrid Papers with Enhanced Electrical and Mechanical Performance and Their Synergy in Polymer Laminatescitations
- 2020Free-standing graphene oxide and carbon nanotube hybrid papers with enhanced electrical and mechanic performance and their synergy in polymer laminatescitations
- 2019Polymer of Intrinsic Microporosity (PIM-7) Coating Affects Triphasic Palladium Electrocatalysiscitations
- 2018Polymer of intrinsic microporosity (PIM-7) coating affects triphasic palladium electrocatalysiscitations
- 2018Polymer of Intrinsic Microporosity (PIM-7) Coating Affects Triphasic Palladium Electrocatalysiscitations
- 2016Polymers of intrinsic microporosity in electrochemistry:anion uptake and transport effects in thin film electrodes and in free-standing ionic diode membranescitations
- 2016Polymers of intrinsic microporosity in electrochemistrycitations
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article
Polymers of intrinsic microporosity in electrochemistry
Abstract
<p>Anion uptake and charge transport in a polymer of intrinsic microporosity (here PIM-EA-TB) is investigated for three cases: (i) the oxidation of ferrocene embedded into a thin film of PIM-EA-TB on a glassy carbon electrode, (ii) the reduction of protons absorbed into a thin film of PIM-EA-TB on a platinum electrode, and (iii) the potential-driven transport of anions and protons in an asymmetrically deposited free-standing PIM-EA-TB membrane working as a current rectifier or "ionic diode". In all three cases the competing effects of the diameter and hydrophobicity (size and hydration energy) of the anion are important. For free-standing membranes very high ionic diode rectification ratios (>10<sup>3</sup> at ±1V) are observed in particular for thicker deposits of PIM-EA-TB and for chloride or perchlorate containing electrolyte.</p>