Materials Map

Discover the materials research landscape. Find experts, partners, networks.

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The Materials Map is an open tool for improving networking and interdisciplinary exchange within materials research. It enables cross-database search for cooperation and network partners and discovering of the research landscape.

The dashboard provides detailed information about the selected scientist, e.g. publications. The dashboard can be filtered and shows the relationship to co-authors in different diagrams. In addition, a link is provided to find contact information.

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The Materials Map is still under development. In its current state, it is only based on one single data source and, thus, incomplete and contains duplicates. We are working on incorporating new open data sources like ORCID to improve the quality and the timeliness of our data. We will update Materials Map as soon as possible and kindly ask for your patience.

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Naji, M.
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Motta, Antonella
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Aletan, Dirar
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Ali, M. A.
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Popa, V.
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Ollier, Nadège
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Azevedo, Nuno Monteiro
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Rignanese, Gian-Marco
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Tedim, J.

  • Google
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in Cooperation with on an Cooperation-Score of 37%

Topics

Publications (22/22 displayed)

  • 2021Insights into corrosion behaviour of uncoated Mg alloys for biomedical applications in different aqueous media10citations
  • 2021Insights into corrosion behaviour of uncoated Mg alloys for biomedical applications in different aqueous media10citations
  • 2020Layered double hydroxides (LDHs) as functional materials for the corrosion protection of aluminum alloys: A review145citations
  • 2019Layered Double Hydroxide Clusters as Precursors of Novel Multifunctional Layers: A Bottom-Up Approach21citations
  • 2018A novel bilayer system comprising LDH conversion layer and sol-gel coating for active corrosion protection of AA202489citations
  • 2017PEO Coatings with Active Protection Based on In-Situ Formed LDH-Nanocontainers79citations
  • 2017How Density Functional Theory Surface Energies May Explain the Morphology of Particles, Nanosheets, and Conversion Films Based on Layered Double Hydroxides33citations
  • 2017Hierarchically organized Li–Al-LDH nano-flakes: a low-temperature approach to seal porous anodic oxide on aluminum alloys39citations
  • 2016Corrosion protection of AA2024-T3 by LDH conversion films. Analysis of SVET results105citations
  • 2016Sealing of tartaric sulfuric (TSA) anodized AA2024 with nanostructured LDH layers90citations
  • 2016Corrosion protection of AA2024 by sol–gel coatings modified with MBT-loaded polyurea microcapsules119citations
  • 2016Interlayer intercalation and arrangement of 2-mercaptobenzothiazolate and 1,2,3-benzotriazolate anions in layered double hydroxides: In situ X-ray diffraction study105citations
  • 2015Polyelectrolyte-modified layered double hydroxide nanocontainers as vehicles for combined inhibitors96citations
  • 2014Active sensing coating for early detection of corrosion processes69citations
  • 2012Chitosan-based self-healing protective coatings doped with cerium nitrate for corrosion protection of aluminum alloy 2024137citations
  • 2011Modulating spectroelectrochemical properties of [Ni(salen)] polymeric films at molecular level31citations
  • 2011Self-healing protective coatings with "green" chitosan based pre-layer reservoir of corrosion inhibitor146citations
  • 2010Solid-State Electrochromic Cells Based on [M(salen)]-Derived Electroactive Polymer Films15citations
  • 2010Structural and electrochemical characterisation of [Pd(salen)]-type conducting polymer films28citations
  • 2009Modulation of electroactive polymer film dynamics by metal ion complexation and redox switching7citations
  • 2008Preparation and characterization of poly[Ni(salen)(crown receptor)]/multi-walled carbon nanotube composite films31citations
  • 2007Correlating structure and ion recognition properties of [Ni(salen)]-based polymer films36citations

Places of action

Chart of shared publication
Neves, C. S.
2 / 2 shared
Freitas, M. A.
1 / 1 shared
Sousa, L.
1 / 4 shared
Almeida, A.
2 / 78 shared
Fraga, S.
2 / 10 shared
Scharnagl, N.
3 / 45 shared
Teixeira, J. P.
1 / 9 shared
Zheludkevich, M. L.
12 / 70 shared
Costa, C.
2 / 13 shared
Ferreira, M. G. S.
12 / 27 shared
Pinto, Edgar
1 / 1 shared
Moreira, L.
1 / 1 shared
Freitas, Ma
1 / 1 shared
Teixeira, Jp
1 / 2 shared
Almeida, Agostinho
1 / 1 shared
Pinto, E.
1 / 4 shared
Sousa, I.
1 / 1 shared
Neves, Cs
1 / 2 shared
Ferreira, Mgs
1 / 5 shared
Zheludkevich, Ml
2 / 3 shared
Serdechnova, M.
5 / 30 shared
Ferreira, M.
2 / 21 shared
Zheludkevich, M.
2 / 42 shared
Blawert, C.
2 / 172 shared
Bouali, A.
1 / 4 shared
Bastos, A.
1 / 4 shared
Rocha, D.
1 / 1 shared
Salak, A.
1 / 2 shared
Cunha, A.
1 / 7 shared
Starykevich, M.
4 / 11 shared
Neves, C.
1 / 1 shared
Yasakau, K. A.
2 / 8 shared
Kallip, S.
5 / 8 shared
Kuznetsova, A.
2 / 2 shared
Karpushenkov, S.
1 / 5 shared
Mohedano, M.
2 / 34 shared
Kuznetsov, B.
2 / 2 shared
Mendis, C. L.
1 / 40 shared
Gomes, J. R. B.
1 / 1 shared
Galvao, T. L. P.
1 / 1 shared
Mendis, Cl
1 / 8 shared
Nixon, S.
2 / 2 shared
Lamaka, Sv
1 / 3 shared
Hack, T.
2 / 8 shared
Mata, D.
1 / 5 shared
Bastos, A. C.
2 / 4 shared
Oliveira, M. P.
1 / 1 shared
Carneiro, J.
3 / 13 shared
Henriques, T.
1 / 1 shared
Maia, F.
3 / 4 shared
Venancio, J.
1 / 1 shared
Cabral, A.
1 / 1 shared
Barbosa, F. S.
1 / 1 shared
Salak, A. N.
2 / 7 shared
Vieira, D. E. L.
1 / 1 shared
Caetano, A. F.
1 / 1 shared
Silvestre, A. J. D.
1 / 8 shared
Gandini, A.
2 / 6 shared
Fernandes, Susana C. M.
2 / 25 shared
Freire, C. S. R.
2 / 10 shared
Moura, C.
2 / 27 shared
Fonseca, J.
3 / 15 shared
Freire, Cristina
5 / 55 shared
Magalhaes, Al
3 / 6 shared
Hillman, Ar
5 / 16 shared
Patricio, S.
2 / 3 shared
Lisenkov, A.
1 / 3 shared
Pinheiro, C.
1 / 5 shared
Pina, F.
1 / 4 shared
Branco, A.
1 / 2 shared
Jorge Parola, Aj
1 / 1 shared
Carneiro, A.
2 / 2 shared
Biernacki, K.
1 / 3 shared
Gurman, Sj
2 / 2 shared
Freire, C.
1 / 21 shared
Figueiredo, Jl
1 / 10 shared
Pereira, Mfr
1 / 32 shared
Goncalves, F.
1 / 4 shared
Bessada, R.
1 / 1 shared
Chart of publication period
2021
2020
2019
2018
2017
2016
2015
2014
2012
2011
2010
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2008
2007

Co-Authors (by relevance)

  • Neves, C. S.
  • Freitas, M. A.
  • Sousa, L.
  • Almeida, A.
  • Fraga, S.
  • Scharnagl, N.
  • Teixeira, J. P.
  • Zheludkevich, M. L.
  • Costa, C.
  • Ferreira, M. G. S.
  • Pinto, Edgar
  • Moreira, L.
  • Freitas, Ma
  • Teixeira, Jp
  • Almeida, Agostinho
  • Pinto, E.
  • Sousa, I.
  • Neves, Cs
  • Ferreira, Mgs
  • Zheludkevich, Ml
  • Serdechnova, M.
  • Ferreira, M.
  • Zheludkevich, M.
  • Blawert, C.
  • Bouali, A.
  • Bastos, A.
  • Rocha, D.
  • Salak, A.
  • Cunha, A.
  • Starykevich, M.
  • Neves, C.
  • Yasakau, K. A.
  • Kallip, S.
  • Kuznetsova, A.
  • Karpushenkov, S.
  • Mohedano, M.
  • Kuznetsov, B.
  • Mendis, C. L.
  • Gomes, J. R. B.
  • Galvao, T. L. P.
  • Mendis, Cl
  • Nixon, S.
  • Lamaka, Sv
  • Hack, T.
  • Mata, D.
  • Bastos, A. C.
  • Oliveira, M. P.
  • Carneiro, J.
  • Henriques, T.
  • Maia, F.
  • Venancio, J.
  • Cabral, A.
  • Barbosa, F. S.
  • Salak, A. N.
  • Vieira, D. E. L.
  • Caetano, A. F.
  • Silvestre, A. J. D.
  • Gandini, A.
  • Fernandes, Susana C. M.
  • Freire, C. S. R.
  • Moura, C.
  • Fonseca, J.
  • Freire, Cristina
  • Magalhaes, Al
  • Hillman, Ar
  • Patricio, S.
  • Lisenkov, A.
  • Pinheiro, C.
  • Pina, F.
  • Branco, A.
  • Jorge Parola, Aj
  • Carneiro, A.
  • Biernacki, K.
  • Gurman, Sj
  • Freire, C.
  • Figueiredo, Jl
  • Pereira, Mfr
  • Goncalves, F.
  • Bessada, R.
OrganizationsLocationPeople

article

Correlating structure and ion recognition properties of [Ni(salen)]-based polymer films

  • Gurman, Sj
  • Freire, Cristina
  • Magalhaes, Al
  • Hillman, Ar
  • Carneiro, A.
  • Patricio, S.
  • Bessada, R.
  • Tedim, J.
Abstract

The structural origins of ion recognition by electrochemically addressable poly[Ni(salen)] thin films are explored using in situ X-ray spectroscopy. XANES and EXAFS provided the local environment (nearest and next-nearest neighbours) around the Ni atom and solution-derived Ba2+ bound to the film. The Ni is covalently bound to two N and two O donors in square planar geometry, irrespective of film redox state and the presence (or absence) of bound Ba2+. The role of the Ni is purely structural; dramatic changes in i-E response accompanying Ba2+ uptake are assigned to the delocalised poly(salen) polymer spine. Ba2+ is trapped in a pseudo-crown formed by two methoxy O donors and two O donors shared with the Ni atom. The Ba2+ EXAFS signal from thick films (10 mu m) is significantly below that anticipated from electrochemical observations on thin films (<100 nm). Since EXAFS and XANES integrate populations over the entire film, this suggests that slow transport restricts Ba2+ access to the outer region of the film; surface sensitive XPS data confirm this. Combination of spectroscopic and electrochemical data suggest that, for exposure times of ca. 10(3) s, only sites in the outer ca. 1 mu m of the film are occupied; the implied diffusion coefficient of 10(-11) cm(2) s(-1) is consistent with a relatively compact solvated film.

Topics
  • impedance spectroscopy
  • surface
  • polymer
  • thin film
  • x-ray photoelectron spectroscopy
  • extended X-ray absorption fine structure spectroscopy