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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Kočí, Jan | Prague |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Böcking, Till
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article
Diazonium salts
Abstract
<p>The modification of gold electrodes with 4-carboxyphenyl diazonium salts to form stable layers for sensing applications is reported. Electrochemical reduction of 4-carboxyphenyl diazonium salts on gold electrodes yielded more stable layers than alkanethiol self-assembled monolayers in terms of extremes of electrode potential, sonication and with time. The application of the 4-carboxyphenyl modified electrodes for electrochemical sensing, which typically requires short chain alkanethiols on gold electrodes, is demonstrated via the covalent attachment of oligopeptides for the selective detection of Cu<sup>2+</sup>, Cd<sup>2+</sup> and Pb<sup>2+</sup>. The diazonium salt/peptide modified gold electrodes not only had greater stability but also performed with lowest detected concentration to alkanethiol/peptide modified electrodes and with far greater sensitivity than the metal ion sensors when diazonium salt/peptide modified similar glassy carbon electrodes were employed.</p>