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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Liu, Xi
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (8/8 displayed)
- 2023The selective oxidation of methane to methanol using in situ generated H 2 O 2 over palladium-based bimetallic catalysts †citations
- 2022Enhancing the Chemo-Enzymatic One-Pot Oxidation of Cyclohexane via in situ H2O2 production over supported Pd-based catalystscitations
- 2020Reduction and carburization of iron oxides for Fischer–Tropsch synthesiscitations
- 2019Promotion Mechanisms of Au Supported on TiO2 in Thermal- And Photocatalytic Glycerol Conversioncitations
- 2019Promotion Mechanisms of Au Supported on TiO 2 in Thermal- And Photocatalytic Glycerol Conversioncitations
- 2019Promotion mechanisms of Au supported on TiO2 in thermal- and photocatalytic glycerol conversioncitations
- 2012Current Status in Fabrication, Structural and Transport Property Characterization, and Theoretical Understanding of Bi2Te3 / Sb2Te3 Superlattice Systemscitations
- 2006The effects of small amounts of H2O, CO2 and Na2O on the partial melting of spinel Lherzolite in the system CaO-MgO-Al2O3-SiO2 ± H2O ± CO2 ± Na2O at 1·1GPacitations
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article
Reduction and carburization of iron oxides for Fischer–Tropsch synthesis
Abstract
The activation of iron oxide Fischer–Tropsch synthesis (FTS) catalysts was investigated during pretreatment: reduction in hydrogen followed by carburization in either CO or syngas mixture, or simultaneously reduction and carburization in syngas. A combination of different complementary in situ techniques was used to gain insight into the behavior of Fe-based FTS catalysts during activation. In situ XRD was used to identify the crystalline structures present during both reduction in hydrogen and carburization. An increase in reduction rate was established when increasing the temperature. A complete reduction was demonstrated in the ETEM and a grain size dependency was proven, i.e. bigger grains need higher temperature in order to reduce. XPS and XAS both indicate the formation of a small amount of carbonaceous species at the surface of the bulk metallic iron during carburization.