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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Barrachin, Marc
Institut de Radioprotection et de Sûreté Nucléaire
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (17/17 displayed)
- 2024Revisiting the thermodynamic properties of the ZrCr2 Laves phases by combined approach using experimental and simulation methodscitations
- 2021Hafnium Oxidation at High Temperature in Steamcitations
- 2019Critical evaluation of experimental data of solution enthalpy of zirconium in liquid aluminumcitations
- 2019Interrupted heating DTA for liquidus temperature determination of Ag–Cd–In alloyscitations
- 2019Hafnium Oxidation in steam at high Temperature
- 2016Core melt composition at Fukushima Daiichi Results of transient simulations with ASTECcitations
- 2014Fuel and fission product behaviour in early phases of a severe accident. Part II Interpretation of the experimental results of the PHEBUS FPT2 testcitations
- 2014Oxidation effect on steel corrosion and thermal loads during corium melt in-vessel retentioncitations
- 2014Fuel and fission product behaviour in early phases of a severe accident. Part I Experimental results of the PHEBUS FPT2 testcitations
- 2013Late phase fuel degradation in the Phébus FP testscitations
- 2013Early phase fuel degradation in Phébus FP: Initiating phenomena of degradation in fuel bundle testscitations
- 2011Ternary eutectics in the systems FeO-UO2-ZrO2 and Fe2O3-U3O8-ZrO2citations
- 2011First-principles study of defect behavior in irradiated uranium monocarbidecitations
- 2007Phase diagram of the UO2-FeO1+x systemcitations
- 2007Progress in nuclear thermodynamic databanking for MCCI applications
- 2006Phase relations in the ZrO2-FeO systemcitations
- 2006Phase diagram of the ZrO2-FeO systemcitations
Places of action
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article
Critical evaluation of experimental data of solution enthalpy of zirconium in liquid aluminum
Abstract
The aim of the present paper is to propose a new interpretation of the zirconium dissolution in liquid aluminum calorimetry experiments performed in the past in order to reconcile some apparently contradictory results and observations. It is supported by the development of a dissolution kinetics model. We show that probably most of the experiments interpreted in terms of dissolution must be considered in terms of (partial or total) transformation of zirconium into zirconium aluminide (Al 3 Zr). In addition, on the basis of the developed model, we propose some recommendations in terms of experimental conditions to improve the dissolution process. These recommendations are consistent with some empirical rules derived in the past. It also puts in question past standard enthalpy measurements of some compounds in the Cu-Zr, Ni-Zr, Co-Zr and U-Zr systems.