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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Braga, Mh
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (18/18 displayed)
- 2021Direct growth of MoS2 on electrolytic substrate and realization of high-mobility transistorscitations
- 2021Structural Batteries: A Reviewcitations
- 2021An All-Solid-State Coaxial Structural Battery Using Sodium-Based Electrolytecitations
- 2020Performance of a ferroelectric glass electrolyte in a self-charging electrochemical cell with negative capacitance and resistancecitations
- 2020Experimental and ab initio study of the Ag-Li system for energy storage and high-temperature solderscitations
- 2018Formation enthalpy of Ga-Li intermetallic phases. Experiment vs. calculationscitations
- 2018Extraordinary Dielectric Properties at Heterojunctions of Amorphous Ferroelectricscitations
- 2017Electric Dipoles and Ionic Conductivity in a Na+ Glass Electrolytecitations
- 2017First principles, thermal stability and thermodynamic assessment of the binary Ni-W systemcitations
- 2017Alternative strategy for a safe rechargeable batterycitations
- 2015Theoretical investigation of defect structure in B2 TrSc (Tr=Cd, Ru) alloyscitations
- 2014Li-Si phase diagram: Enthalpy of mixing, thermodynamic stability, and coherent assessmentcitations
- 2014Optimization and assessment of the Ag-Ca phase diagramcitations
- 2013Experimental and First Principles Study of the Ni-Ti-W Systemcitations
- 2012Study of the Cu-Li-Mg-H system by thermal analysiscitations
- 2010Neutron powder diffraction and first-principles computational studies of CuLixMg2-x (x congruent to 0.08), CuMg2, and Cu2Mgcitations
- 2007THE BEHAVIOUR OF THE LATTICE PARAMETERS IN THE Bi-Sn-Zn SYSTEMcitations
- 2000The Cu-Li-Mg system at room temperaturecitations
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article
Formation enthalpy of Ga-Li intermetallic phases. Experiment vs. calculations
Abstract
The solution calorimetric method was applied to determine the heat of solution of liquid gallium in the liquid tin and the standard enthalpies of formation of the Ga64.3Li35.7 alloy (composition corresponds to the Ga9Li5 intermetallic phase), and GaLi, Ga2Li3 intermetallic phases. These alloys were prepared from pure, metallic Ga and Li, which were melted in a glove-box filled with high purity argon with a very low concentration of impurities. All experiments were performed with the use of a Setaram MHTC 96 Line evo calorimeter. The heat of solution (limiting partial enthalpy of solution) of gallium in a Sn-bath shows a temperature dependence. The standard enthalpies of formation of the Ga64.3Li35.7 (Ga9Li5), GaLi and Ga2Li3 intermetallic phases, were measured at 723 K; the obtained values were -26.7 +/- 1.4, -33.5 +/- 2.0, and -31.1 +/- 2.0 kJ/mol at., respectively. First principles calculations were performed to determine the enthalpies of formation of each compound. It was found that the latter are in much better agreement with the experimental data than those obtained with the Miedema model. (C) 2018 Elsevier Ltd.