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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Prostakova, Viktoria
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (7/7 displayed)
- 2023Experimental Study and Thermodynamic Modelling of Equilibrium Distributions of Ni, Sn and Zn Between Slag and Black Copper for E-Scrap Recycling Applicationscitations
- 2022Review and thermodynamic analysis of As (arsenic) in copper smelting liquid mattes, metals, slags, speiss and solid phases
- 2019Integrated experimental and thermodynamic modelling research for primary and recycling pyrometallurgy
- 2015Experimental investigation and thermodynamic modeling of the (NiO + CaO + SiO2), (NiO + CaO + MgO) and (NiO + CaO + MgO + SiO2) systemscitations
- 2013Experimental study and thermodynamic modeling of the MgO–NiO–SiO2 systemcitations
- 2012Experimental study and thermodynamic optimization of the CaO-NiO, MgO-NiO and NiO-SiO2 systemscitations
- 2012Development of NiO-CaO-MgO-SiO2 thermodynamic database using experimental and thermodynamic modelling approaches with focus on NiO-MgO-SiO2 and NiO-CaO-SiO2 systems
Places of action
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article
Experimental investigation and thermodynamic modeling of the (NiO + CaO + SiO2), (NiO + CaO + MgO) and (NiO + CaO + MgO + SiO2) systems
Abstract
The (NiO + CaO + MgO + SiO) system and its ternary subsystems (NiO + CaO + MgO) and (NiO + CaO + SiO) have been studied by a combination of thermodynamic modeling and experimental measurements of phase equilibria. A complete literature review and critical evaluation of phase diagrams and thermodynamic properties of all oxide phases in these systems at 1 atm total pressure are presented. To resolve the contradictions in the literature data for the (NiO + CaO + SiO) system, a new experimental investigation has been carried out over the temperature range from (1330 to 1500) °C using an equilibration and quenching technique followed by electron probe X-ray microanalysis (EPMA). The compositions of phases for equilibria among liquid, pseudo-wollastonite, clino-pyroxene, olivine and tridymite have been measured. The whole set of experimental data, including the new experimental results and previously published data, is taken into consideration in thermodynamic modeling of oxide phases and optimization of model parameters. The Modified Quasichemical Model is used for the liquid phase. The models for olivine, melilite and pyroxene solid solutions are developed within the framework of the Compound Energy Formalism. A self-consistent set of thermodynamic functions of all phases in the (NiO + CaO + MgO + SiO) system is obtained, which reproduces all available thermodynamic and phase diagram data within experimental error limits.