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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Schroder, B.
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Topics
Publications (4/4 displayed)
- 2007Thermochemical studies of five crystalline bis(O-alkyl-N-thenoylthiocarbamato)nickel(II) complexescitations
- 2004Standard molar enthalpies of formation of two crystalline bis[N-(diethylaminothiocarbonyl)benzamidinato]nickel(II) complexescitations
- 2004Standard molar enthalpies of formation of two crystalline bis[N-(diethylaminothiocarbonyl)benzamidinato]nickel(II) complexescitations
- 2004Thermochemical studies of three bis(O-alkyl-N-benzoylthiocarbamato)nickel(II) complexescitations
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article
Standard molar enthalpies of formation of two crystalline bis[N-(diethylaminothiocarbonyl)benzamidinato]nickel(II) complexes
Abstract
The standard (p°=0.1 MPa) molar enthalpies of formation of the crystalline complexes bis[N-(N″,N″-diethylaminothiocarbonyl) benzamidinato]nickel(II), {Ni(datb)2}, and bis[N-(N″,N″- diethylaminothiocarbonyl)-N′-phenylbenzamidinato]nickel(II), {Ni(datpb)2}, were determined, at T=298.15 K, by high precision solution-reaction calorimetry. ΔfHm°(cr)/ (kJ·mol-1)Ni(datb)26.5 ± 7.9Ni(datpb) 2285.1 ± 11.3 From the obtained results, the metal-ligand exchange enthalpies in the crystalline phase were derived. The enthalpy of a hypothetical metal-ligand exchange reaction in the crystalline phase was derived, thus allowing a discussion of the energetics of complexation in comparison with known crystal-structural parameters.