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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Schroder, B.
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Publications (4/4 displayed)
- 2007Thermochemical studies of five crystalline bis(O-alkyl-N-thenoylthiocarbamato)nickel(II) complexescitations
- 2004Standard molar enthalpies of formation of two crystalline bis[N-(diethylaminothiocarbonyl)benzamidinato]nickel(II) complexescitations
- 2004Standard molar enthalpies of formation of two crystalline bis[N-(diethylaminothiocarbonyl)benzamidinato]nickel(II) complexescitations
- 2004Thermochemical studies of three bis(O-alkyl-N-benzoylthiocarbamato)nickel(II) complexescitations
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article
Thermochemical studies of three bis(O-alkyl-N-benzoylthiocarbamato)nickel(II) complexes
Abstract
The standard (pdegrees = 0.1 MPa) molar enthalpies of formation of the crystalline complexes of Ni(II) with three N-benzoylthiocarbamic-O-alkylesters, PhCONHCSOR, R = Et, n-Bu, n-Hex were determined, at T = 298.15 K, by high precision solution and reaction calorimetry. Complex -Delta(f)H(m)degrees(cr)/(kJ (.) mol(-1)) Ni(PhCONCSOEt)(2) 619.2 +/- 6.1 Ni(PhCONCSO-n-Bu)(2) 707.4 +/- 6.2 Ni(PhCONCSO-n-Hex)(2) 802.6 +/- 8.3 From the obtained results, the metal-ligand exchange enthalpies in the crystalline phase were derived, indicating that the increase of the ester-alkyl chain length in these compounds do not significantly affect the difference between the metal-to-ligand-binding enthalpy and the hydrogen-binding enthalpy, {D(M-L) - D(H-L)}.