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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Alam, Firoz
University of Manchester
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (13/13 displayed)
- 2024Doping Up the Light: A Review of A/B-Site Doping in Metal Halide Perovskite Nanocrystals for Next-Generation LEDs.
- 2023A Low‐Temperature Synthetic Route Toward a High‐Entropy 2D Hexernary Transition Metal Dichalcogenide for Hydrogen Evolution Electrocatalysiscitations
- 2023A Low‐Temperature Synthetic Route Toward a High‐Entropy 2D Hexernary Transition Metal Dichalcogenide for Hydrogen Evolution Electrocatalysiscitations
- 2023The race between complicated multiple cation/anion compositions and stabilization of FAPbI3 for halide perovskite solar cells
- 2022Investigating the effect of steric hindrance within CdS single-source precursors on the material properties of AACVD and spin coat-deposited CdS thin filmscitations
- 2021Direct Synthesis of Nanostructured Silver Antimony Sulfide Powders from Metal Xanthate Precursorscitations
- 2021Testing the Efficacy of the Synthesis of Iron Antimony Sulfide powders from Single Source Precursorscitations
- 2021Molecular Precursor Route to Bournonite (CuPbSbS3) Thin Films and Powderscitations
- 2021Structural investigations of α-MnS nanocrystals and thin films synthesised from manganese(II) xanthates by hot injection, solvent-less thermolysis and doctor blade routes.citations
- 2021Synthesis of molybdenum-doped rhenium disulfide alloy using aerosol-assisted chemical vapour depositioncitations
- 2021Testing the Efficacy of the Synthesis of Iron Antimony Sulfide Powders from Single Source Precursorscitations
- 2019Synthesis of Iron Sulfide Thin Films and Powders from New Xanthate Precursorscitations
- 2019A molecular precursor route to quaternary chalcogenide CFTS (Cu2FeSnS4) powders as potential solar absorber materialscitations
Places of action
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article
Synthesis of Iron Sulfide Thin Films and Powders from New Xanthate Precursors
Abstract
A series of novel alkylxanthato iron(III) precursors [Fe(S2COR)3] (R = n-butyl, (1); 2-butyl, (2); 2-methoxyethyl, (3); and 2-ethoxyethyl (4)) have been synthesised and their single crystal X-ray structures have been studied. All as-synthesised complexes were used as single-source precursors for the deposition of iron sulfide thin films as well as nanostructures using spin coating technique and solventless thermolysis respectively. Cubic pyrite was obtained using n-butyl xanthato iron(III) and 2-butyl xanthato iron(III) complexes in the temperature range of 200 to 300°C. Structural and morphological investigations using XRD and SEM have been performed to ascertain the crystallinity and morphology of as-prepared thin films and nanostructures. The elemental composition was determined using energy dispersive X-ray (EDX) spectroscopy. The optical band gaps of pyrite thin films produced by these methods were direct with estimated values in the range 1.6 to 2.3 eV.