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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Saha, Basudeb
Lancaster University
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (11/11 displayed)
- 2022Synthesis of green thermo-responsive amphoteric terpolymer functionalized silica nanocomposite derived from waste vegetable oil triglycerides for enhanced oil recovery (EOR)citations
- 2019Synthesis and characterization of a novel amphoteric terpolymer nanocomposite for enhanced oil recovery applications
- 2019Synthesis and characterization of a novel amphoteric terpolymer nanocomposite for enhanced oil recovery applications
- 2019Systematic multivariate optimisation of butylene carbonate synthesis via CO <inf>2</inf> utilisation using graphene-inorganic nanocomposite catalystscitations
- 2018Greener synthesis of dimethyl carbonate using a novel tin-zirconia/graphene nanocomposite catalystcitations
- 2018A facile and greener synthesis of butylene carbonate via CO2 utilisation using a novel copper–zirconia oxide/graphene catalyst
- 2018Greener synthesis of butylene carbonate via CO2 utilisation using graphene-inorganic nanocomposite catalysts
- 2018Greener synthesis of 1,2-butylene carbonate from CO2 using graphene-inorganic nanocomposite catalystcitations
- 2017Greener synthesis of styrene carbonate from CO2 using graphene-inorganic nanocomposite catalysts
- 2017Greener synthesis of 1, 2 butylene carbonate from CO2 using graphene-inorganic nanocomposite catalysis
- 2017Carbon dioxide utilization by graphene based nanocomposite materials as catalysts
Places of action
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article
Synthesis of green thermo-responsive amphoteric terpolymer functionalized silica nanocomposite derived from waste vegetable oil triglycerides for enhanced oil recovery (EOR)
Abstract
Despite the high efficiency of polymer flooding as a chemical enhanced oil recovery (CEOR) technique, the low thermal stability and poor salt resistance of widely applied partially hydrolyzed polyacrylamide (HPAM) limited the application of this technique in oil reservoirs at harsh reservoir conditions of high–temperature and high–salinity (HTHS). These inadequacies of HPAM, result in the urge for an environmentally friendly polymer with good viscosifying properties and a substantial effect on mobility ratio at HTHS reservoir conditions. In this research, a high oleic acid waste vegetable oil (WVO) is utilized to synthesize a novel environmentally benign, thermo-responsive amphoteric nanocomposite for EOR applications at HTHS reservoir conditions. A green route transesterification reaction has been utilized to synthesize a novel thermo-sensitive monomer from WVO. The existence of unsaturated fatty acids isolated double bonds and acryloyl functional groups in the synthesized monomer has been confirmed using different characterization methods. The reactive acryloyl double bond in the synthesized monomer has been copolymerized with acrylamide, acrylacyloxyethyltrimethyl ammonium chloride, and 2-acrylamide-2-methylpropane sulfonic acid in presence of dimethylphenylvinylsilane via free radical emulsion polymerization. The synthesized nanocomposite has been characterized by FTIR, 1H NMR, SEM, EDX, TEM, and DLS. The thermal stability of the nanocomposite has been evaluated by TGA and DTA analysis. The results indicated that nanocomposite solution exhibited a pouncing thermo-thickening behaviour and superior viscosifying properties even at an ultra-low polymer concentration of 0.04 wt.% as the temperature increased from 25 to 100 °C, with increasing salinity from 10,000 to 230,000 ppm as well as salt-free solutions. Flooding experiments demonstrated that the oil recovery factor reached 15.4 ± 0.1% using low nanocomposite concentrations of 0.04 wt.%, 22.6 ± 0.3% using nanocomposite concentrations of 0.06 wt.% and 25 ± 0.2% using 0.1 wt.% nanocomposite concentrations evaluated under hostile conditions of 100 °C and salinity of about 230,000 ppm. This research offers a new direction for the synthesis of a novel green, high molecular weight thermo-responsive nanocomposite for EOR application at extremely harsh reservoir conditions via WVO valorization.