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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Wießner, Sven
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (16/16 displayed)
- 2024Unlocking the Potential of Lignin: Towards a Sustainable Solution for Tire Rubber Compound Reinforcementcitations
- 2022Electrically conductive and piezoresistive polymer nanocomposites using multiwalled carbon nanotubes in a flexible copolyester: Spectroscopic, morphological, mechanical and electrical properties
- 2022Thermoelectric Performance of Polypropylene/Carbon Nanotube/Ionic Liquid Composites and Its Dependence on Electron Beam Irradiationcitations
- 2021First-Time Investigations on Cavitation in Rubber Parts Subjected to Constrained Tension Using In Situ Synchrotron X-Ray Microtomography (SRμCT)citations
- 2021Treasuring waste lignin as superior reinforcing filler in high cis-polybutadiene rubbercitations
- 2021Fundamentals and working mechanisms of artificial muscles with textile application in the loopcitations
- 2021A new strategy to improve viscoelasticity, crystallization and mechanical properties of polylactidecitations
- 2021Improved rheology, crystallization, and mechanical performance of PLA/mPCL blends prepared by electron-induced reactive processingcitations
- 2020Friction, abrasion and crack growth behavior of in-situ and ex-situ silica filled rubber compositescitations
- 2018Development and testing of controlled adaptive fiber-reinforced elastomer composites.citations
- 2018Development and testing of controlled adaptive fiber-reinforced elastomer compositescitations
- 2018Blending In Situ Polyurethane-Urea with Different Kinds of Rubber: Performance and Compatibility Aspectscitations
- 2017Strong Strain Sensing Performance of Natural Rubber Nanocompositescitations
- 2017Benefits of hybrid nano-filler networking between organically modified Montmorillonite and carbon nanotubes in natural rubber: Experiments and theoretical interpretations
- 2017Temperature-Dependent Reinforcement of Hydrophilic Rubber Using Ice Crystals
- 2006Effects of interface reactions in complatibilised ground tyre rubber polypropylene etastomeric alloyscitations
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article
Treasuring waste lignin as superior reinforcing filler in high cis-polybutadiene rubber
Abstract
<p>There has been ever raising concern in last few decades about the utilization of biomass for different commercial applications such as filler materials in rubber composites. In this context, an interesting pathway has been proposed to develop such composites by introducing waste lignin as a reinforcing constituent in high cis-polybutadiene rubber (BR). With a judicious selection of rubber curing ingredients and, simultaneously, adopting suitable solid-state mixing protocols, particularly, a relatively high-temperature multi-steps melt-mixing process (above the glass transition temperature of lignin), rubber composites with an outstanding mechanical performance were prepared. The reinforced rubber composites with 50 (weight) parts lignin loading per hundred parts of rubber (phr) offer ∼10 MPa tensile strength (TS), ∼276% elongation at break (EB), and ∼3.51 MPa tensile stress at 100% elongation (so-called rubber modulus M<sub>100</sub>). These values are superior when compared with the composites comprised with standard reinforcing carbon black (∼8.5 TS, ∼224% EB, ∼2.79 M<sub>100</sub>) and even with a silica-silane system (∼7.34 TS, ∼229% EB, ∼2.44 M<sub>100</sub>) with same filler loading. The unique combination of the curing packages and four-stage mixing process allowed us to establish a homogeneous and fine dispersion of lignin. Furthermore, this is the first time that available models of rubber reinforcement are applied to the description of the reinforcement mechanisms of lignin in a soft elastomer involving various aspects like filler-filler interaction, rubber-filler interactions, critical strains for destroying the filler-filler network, effective filler volume fractions, shape factor, etc. The developed compounding methods for BR and their characterization and modeling can be easily applied to other commercial rubbers facilitating a real breakthrough in developing cheap and bio-based high-performance rubber composites.</p>