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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Liu, Ning
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Publications (5/5 displayed)
- 2023Quantitative surface free energy with micro-colloid probe pairscitations
- 2021Reduced grey brookite for noble metal free photocatalytic H2 evolutioncitations
- 2021Hydrogenated anatase TiO2 single crystals: defects formation and structural changes as microscopic origin of co-catalyst free photocatalytic H2 evolution activitycitations
- 2019Photocatalysis with Reduced TiO2: From Black TiO2 to Cocatalyst-Free Hydrogen Productioncitations
- 2018A direct synthesis of platinum/nickel co-catalysts on titanium dioxide nanotube surface from hydrometallurgical-type process streamscitations
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article
A direct synthesis of platinum/nickel co-catalysts on titanium dioxide nanotube surface from hydrometallurgical-type process streams
Abstract
Solutions that simulate hydrometallurgical base metal process streams with high nickel (Ni) and minor platinum (Pt) concentrations were used to create Pt/Ni nanoparticles on TiO<sub>2</sub> nanotube surfaces. For this, electrochemical deposition – redox replacement (EDRR) was used that also allowed to control the nanoparticle size, density and Pt/Ni content of the deposited nanoparticles The Pt/Ni nanoparticle decorated titanium dioxide nanotubes (TiO<sub>2</sub> nanotubes) become strongly activated for photocatalytic hydrogen (H<sub>2</sub>) evolution. Moreover, EDRR facilitates nanoparticle formation without the need for any additional chemicals and is more effective than electrodeposition alone. Actually, a 10,000-time enrichment level of Pt took place on the TiO<sub>2</sub> surface when compared to Pt content in the solution with the EDRR method. The results show that hydrometallurgical streams offer great potential as an alternative raw material source for industrial catalyst production when coupled with redox replacement electrochemistry.