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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Mautner, Andreas
University of Natural Resources and Life Sciences, Vienna
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (26/26 displayed)
- 2024Low-Temperature controlled synthesis of nanocast mixed metal oxide spinels for enhanced OER activitycitations
- 2024Fungal Carbon: A Cost-Effective Tunable Network Template for Creating Supercapacitorscitations
- 20233D printed polylactic acid (PLA) filters reinforced with polysaccharide nanofibers for metal ions capture and microplastics separation from watercitations
- 20233D printed polylactic acid (PLA) filters reinforced with polysaccharide nanofibers for metal ions capture and microplastics separation from watercitations
- 2023Sulfonated hypercrosslinked polymer enhanced structural composite supercapacitorscitations
- 2022Facile Preparation of Mechanically Robust and Functional Silica/Cellulose Nanofiber Gels Reinforced with Soluble Polysaccharidescitations
- 2022Synthesis and comparative performance study of crystalline and partially amorphous nano-sized SnS2 as anode materials for lithium-ion batteriescitations
- 2022Towards robust synchronous belts: influence of surface characteristics on interfacial adhesioncitations
- 2022Modified Polymer Surfaces: Thin Films of Silicate Composites via Polycaprolactone Melt Fusioncitations
- 2022Pilot-scale modification of polyethersulfone membrane with a size and charge selective nanocellulose layercitations
- 2022Pilot-scale modification of polyethersulfone membrane with a size and charge selective nanocellulose layercitations
- 2021Defect {((WO7)-O-VI)W-4(VI)} and Full {((WO7)-O-VI)W-5(VI)} Pentagonal Units as Synthons for the Generation of Nanosized Main Group V Heteropolyoxotungstatescitations
- 2021Interfacial Adhesion and Mechanical Properties of Wood-Polymer Hybrid Composites Prepared by Injection Moldingcitations
- 2021Grow it yourself composites: delignification and hybridisation of lignocellulosic material using animals and fungicitations
- 2021High-Velocity Stretching of Renewable Polymer Blendscitations
- 2021Bacterial nanocellulose papers with high porosity for optimized permeance and rejection of nm-sized pollutantscitations
- 2020Mechanical properties and electrical surface charges of microfibrillated cellulose/imidazole-modified polyketone composite membranescitations
- 2020Mechanical properties and electrical surface charges of microfibrillated cellulose/imidazole-modified polyketone composite membranescitations
- 2020Plastic to elastic: Fungi-derived composite nanopapers with tunable tensile propertiescitations
- 2020High porosity cellulose nanopapers as reinforcement in multi-layer epoxy laminatescitations
- 2020Plastic to elastic : Fungi-derived composite nanopapers with tunable tensile propertiescitations
- 2018Incorporation of CuO nanoparticles into thin-film composite reverse osmosis membranes (TFC-RO) for antibiofouling propertiescitations
- 2018Better togethercitations
- 2018Adhesion properties of regenerated lignocellulosic fibres towards poly(lactic acid) microspheres assessed by colloidal probe techniquecitations
- 2018Adhesion properties of regenerated lignocellulosic fibres towards poly (lactic acid) microspheres assessed by colloidal probe techniquecitations
- 2016Tough Photopolymers Based on Vinyl Esters for Biomedical Applicationscitations
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article
Low-Temperature controlled synthesis of nanocast mixed metal oxide spinels for enhanced OER activity
Abstract
<p>The controlled cation substitution is an effective strategy for optimizing the density of states and enhancing the electrocatalytic activity of transition metal oxide catalysts for water splitting. However, achieving tailored mesoporosity while maintaining elemental homogeneity and phase purity remains a significant challenge, especially when aiming for complex multi-metal oxides. In this study, we utilized a one-step impregnation nanocasting method for synthesizing mesoporous Mn-, Fe-, and Ni-substituted cobalt spinel oxide (Mn<sub>0.1</sub>Fe<sub>0.1</sub>Ni<sub>0.3</sub>Co<sub>2.5</sub>O<sub>4</sub>, MFNCO) and demonstrate the benefits of low-temperature calcination within a semi-sealed container at 150–200 °C. The comprehensive discussion of calcination temperature effects on porosity, particle size, surface chemistry and catalytic performance for the alkaline oxygen evolution reaction (OER) highlights the importance of humidity, which was modulated by a pre-drying step. The catalyst calcined at 170 °C exhibited the lowest overpotential (335 mV at 10 mA cm<sup>−2</sup>), highest current density (433 mA cm<sup>−2</sup> at 1.7 V vs. RHE, reversible hydrogen electrode) and further displayed excellent stability over 22 h (at 10 mA cm<sup>−2</sup>). Furthermore, we successfully adapted this method to utilize cheap, commercially available silica gel as a hard template, yielding comparable OER performance. Our results represent a significant progress in the cost-efficient large-scale preparation of complex multi-metal oxides for catalytic applications.</p>