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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Thormann, Esben
Technical University of Denmark
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (17/17 displayed)
- 2024Reducing Ice Adhesion to Polyelectrolyte Surfaces by Counterion-Mediated Nonfrozen Hydration Watercitations
- 2023A Biomimetic Water-Resistant Adhesive Based on ϵ-Polylysine/Tannic Acid Complexationcitations
- 2023Fibrin Adsorption on Cardiovascular Biomaterials and Medical Devicescitations
- 2021A pH-responsive polyelectrolyte multilayer film with tunable interfacial propertiescitations
- 2021A pH-responsive polyelectrolyte multilayer film with tunable interfacial propertiescitations
- 2021pH-responsive chitosan nanofilms crosslinked with genipincitations
- 2021pH-Responsive Chitosan Nanofilms Crosslinked with Genipincitations
- 2020Water Diffusion in Polymer Composites Probed by Impedance Spectroscopy and Time-Resolved Chemical Imagingcitations
- 2020Surface forces and friction tuned by thermo-responsive polymer filmscitations
- 2020Surface forces and friction tuned by thermo-responsive polymer filmscitations
- 2018An engineered cell-imprinted substrate directs osteogenic differentiation in stem cellscitations
- 2018An engineered cell-imprinted substrate directs osteogenic differentiation in stem cellscitations
- 2014Direct measurement of colloidal interactions between polyaniline surfaces in a uv-curable coating formulation:the effect of surface hydrophilicity/ hydrophobicity and resin compositioncitations
- 2014Direct measurement of colloidal interactions between polyaniline surfaces in a uv-curable coating formulationcitations
- 2013Tribological Properties Mapping: Local Variation in Friction Coefficient and Adhesioncitations
- 2012Adsorption and protein-induced metal release from chromium metal and stainless steelcitations
- 2011Toward Homogeneous Nanostructured Polyaniline/Resin Blendscitations
Places of action
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article
Adsorption and protein-induced metal release from chromium metal and stainless steel
Abstract
A research effort is undertaken to understand the mechanism of metal release from, e.g., inhaled metal particles or metal implants in the presence of proteins. The effect of protein adsorption on the metal release process from oxidized chromium metal surfaces and stainless steel surfaces was therefore examined by quartz crystal microbalance with energy dissipation monitoring (QCM-D) and graphite furnace atomic absorption spectroscopy (GFAAS). Differently charged and sized proteins, relevant for the inhalation and dermal exposure route were chosen including human and bovine serum albumin (HSA, BSA), mucin (BSM), and lysozyme (LYS). The results show that all proteins have high affinities for chromium and stainless steel (AISI 316) when deposited from solutions at pH 4 and at pH 7.4 where the protein adsorbed amount was very similar. Adsorption of albumin and mucin was substantially higher at pH 4 compared to pH 7.4 with approximately monolayer coverage at pH 7.4, whereas lysozyme adsorbed in multilayers at both investigated pH. The protein–surface interaction was strong since proteins were irreversibly adsorbed with respect to rinsing. Due to the passive nature of chromium and stainless steel (AISI 316) surfaces, very low metal release concentrations from the QCM metal surfaces in the presence of proteins were obtained on the time scale of the adsorption experiment. Therefore, metal release studies from massive metal sheets in contact with protein solutions were carried out in parallel. The presence of proteins increased the extent of metals released for chromium metal and stainless steel grades of different microstructure and alloy content, all with passive chromium(III)-rich surface oxides, such as QCM (AISI 316), ferritic (AISI 430), austentic (AISI 304, 316L), and duplex (LDX 2205).