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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Ribitsch, Volker
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (17/17 displayed)
- 2018Optimization of the Catalyst and Membrane Performance by addition of various Additives for the alkaline Direct Ethanol Fuel Cell
- 2015Cellulose thin films from ionic liquid solutions
- 2013Functional patterning of biopolymer thin films using enzymes and lithographic methodscitations
- 2013Chitosan-Silane Sol-Gel Hybrid Thin Films with controllable Layer Thickness and Morphologycitations
- 2013Comparison study of TEMPO and phthalimide-N-oxyl (PINO) radicals on oxidation efficiency toward cellulosecitations
- 2013Chemical modification and characterization of poly(ethylene terephthalate) surfaces for collagen immobilizationcitations
- 2012Adsorption of carboxymethyl cellulose on polymer surfacescitations
- 2011Wettability and surface composition of partly and fully regenerated cellulose thin films from trimethylsilyl cellulosecitations
- 2011Deposition of silicon doped and pure hydrogenated amorphous carbon coatings on quartz crystal microbalance sensors for protein adsorption studiescitations
- 2009Electrokinetic properties of polypropylene-layered silicate Nanocomposite fiberscitations
- 2008Adsorption of chitosan on PET films monitored by quartz crystal microbalancecitations
- 2005Determination of the accessible carboxyl and amino end groups in structurally modified PA 6 using titration methods
- 2004Determination of dissociable groups in natural and regenerated cellulose fibers by different titration methodscitations
- 2004Determining the Surface Free Energy of Cellulose Materials with the Powder Contact Angle Methodcitations
- 2003Characterisation of modified polypropylene fibrescitations
- 2002Modifikacije PA 6 z NH3 plazmo
- 2000Analiza povrsine vlaken z mikroskopijo atomskih sil (AFM)
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article
Wettability and surface composition of partly and fully regenerated cellulose thin films from trimethylsilyl cellulose
Abstract
<p>The wettability and surface free energy (SFE) of partly and fully regenerated cellulose model surfaces from spin coated trimethylsilyl cellulose were determined by static contact angle (SCA) measurements. In order to gain detailed insight into the desilylation reaction of the surfaces the results from SCA measurements were compared with data from other surface analytical methods, namely thickness measurements, X-ray photoelectron spectroscopy (XPS) and attenuated total reflectance infrared spectroscopy (ATR-IR). Additionally, the influence of ultra high vacuum treatment (UHV) during XPS measurements on the water wettability and surface morphology of regenerated cellulose thin films was investigated. The wetting of polar and non-polar liquids increased with prolonged regeneration time, which is reflected in the higher SFE values and polarities of the films. After UHV treatment the water SCA of partly regenerated films decreases, whereas fully regenerated cellulose shows a higher water SCA. Therefore it is assumed that volatile desilylation products tend to adsorb on partly regenerated films, which strongly influences their wettability.</p>