| People | Locations | Statistics |
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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Especel, Catherine
University of Poitiers
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (8/8 displayed)
- 2015Hydrocarbon fuel synthesis from sorbitol over bifunctional catalysts: Association of tungstated titania with platinum, palladium or iridiumcitations
- 2015Selective ring opening of methylcyclohexane and decalin over Rh-Pd supported catalysts: Effect of the preparation methodcitations
- 2012Selective hydrogenation of citral to unsaturated alcohols over mesoporous Pt/Ti-Al2O3 catalysts. Effect of the reduction temperature and of the Ge additioncitations
- 2012Citral hydrogenation on high surface area mesoporous TiO2-SiO2 supported Pt nanocomposites: Effect of titanium loading and reduction temperature on the catalytic performancescitations
- 2011The relationship between the structural properties of bimetallic Pd-Sn/SiO2 catalysts and their performance for selective citral hydrogenation citations
- 2011Catalytic performances of large pore Ti-SBA15 supported Pt nanocomposites for the citral hydrogenation reaction citations
- 2010Control of titania nanodomain size as a route to modulate SMSI effect in Pt/TiO2 catalystscitations
- 2006Bimetallic Rh-Ge and Pt-Ge catalysts supported on TiO2 for citral hydrogenation I. Preparation and characterization of the catalysts citations
Places of action
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article
The relationship between the structural properties of bimetallic Pd-Sn/SiO2 catalysts and their performance for selective citral hydrogenation
Abstract
The effect of Sn addition to Pd on the selective liquid-phase hydrogenation of citral to alpha,beta-unsaturated alcohols (VA: nerol and geraniol) was examined. Pd-Sn/SiO2 bimetallic catalysts were prepared by successive impregnation method and were characterized by transmission electronic microscopy (TEM) coupled with energy dispersive X-ray spectroscopy (EDX), temperature-programmed reduction (TPR), Fourier transform infrared (FFIR) spectroscopy of adsorbed CO, and X-ray photoelectron spectroscopy (XPS). Sn addition to Pd/SiO2 catalysts significantly modifies their properties for citral hydrogenation performed at 130 degrees C, under 7 MPa and in isopropanol solvent, inducing a promoting effect on the VA selectivity. This promoting effect is related to the existence of a Pd-Sn interaction highlighted by EDX analysis, TPR under hydrogen and FTIR of adsorbed CO. The latter technique suggested the presence of a geometric effect on catalytic activity. Maximum VA selectivities (>75% at 30% citral conversion) were obtained when an alloy of the Pd3Sn type is formed in the bimetallic particles, as confirmed by TPR and XPS. Moreover, FTIR measurements of the adsorbed CO singleton frequency as well as XPS binding energy shifts strongly imply an electron transfer from Sn to Pd, which is proposed to be responsible for enhanced adsorption of citral C=O bond on the surface of Pd-Sn/SiO2 bimetallic catalysts. To our knowledge, it is the first time that modified Pd catalysts lead to such important UA selectivity values during alpha,beta-unsaturated aldehyde hydrogenation.