People | Locations | Statistics |
---|---|---|
Naji, M. |
| |
Motta, Antonella |
| |
Aletan, Dirar |
| |
Mohamed, Tarek |
| |
Ertürk, Emre |
| |
Taccardi, Nicola |
| |
Kononenko, Denys |
| |
Petrov, R. H. | Madrid |
|
Alshaaer, Mazen | Brussels |
|
Bih, L. |
| |
Casati, R. |
| |
Muller, Hermance |
| |
Kočí, Jan | Prague |
|
Šuljagić, Marija |
| |
Kalteremidou, Kalliopi-Artemi | Brussels |
|
Azam, Siraj |
| |
Ospanova, Alyiya |
| |
Blanpain, Bart |
| |
Ali, M. A. |
| |
Popa, V. |
| |
Rančić, M. |
| |
Ollier, Nadège |
| |
Azevedo, Nuno Monteiro |
| |
Landes, Michael |
| |
Rignanese, Gian-Marco |
|
Guilmeau, E.
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (19/19 displayed)
- 2021Effects of Grain Size on the Thermoelectric Properties of Cu2SnS3: An Experimental and First-Principles Studycitations
- 2020Structure, microstructure and thermoelectric properties of germanite-type Cu22Fe8Ge4S32 compoundscitations
- 2020Structure, microstructure and thermoelectric properties of germanite-type Cu22Fe8Ge4S32 compoundscitations
- 2018Substituting Copper with Silver in the BiMOCh Layered Compounds (M = Cu or Ag; Ch = S, Se, or Te) Crystal, Electronic Structure, and Optoelectronic Propertiescitations
- 2017The crucial role of selenium for sulphur substitution in the structural transitions and thermoelectric properties of Cu5FeS4 bornitecitations
- 2016Ba 6−3x Nd 8+2x Ti 18 O 54 Tungsten Bronze A New High-Temperature n-Type Oxide Thermoelectriccitations
- 2016Thermoelectric properties of TiS2 mechanically alloyed compoundscitations
- 2015Synthesis and thermoelectric properties in the 2D Ti 1 - x Nb x S 3 trichalcogenidescitations
- 2015On the effects of substitution, intercalation, non-stoichiometry and block layer concept in TiS 2 based thermoelectricscitations
- 2014Electron doping and phonon scattering in Ti1+xS2 thermoelectric compoundscitations
- 2014Thermoelectric properties of In0.2Co4Sb12 skutterudites with embedded PbTe or ZnO nanoparticlescitations
- 2013High temperature thermoelectric properties of CoSb3 skutterudites with PbTe inclusionscitations
- 2011Solution-based synthesis routes to thermoelectric Bi2Ca2Co1.7Oxcitations
- 2011Preparation of Ni-doped ZnO ceramics for thermoelectric applicationscitations
- 2010Transport and magnetic properties of Mo2.5Ru0.5Sb7−xTexcitations
- 2010High thermoelectric power factor in Fe-substituted Mo3Sb7citations
- 2010High thermoelectric power factor in Fe-substituted Mo.sub.3./sub.Sb.sub.7./sub.citations
- 2005Rietveld texture analysis of alumina ceramics by neutron diffractioncitations
- 2005Texture of alumina by neutron diffraction and SEM-EBSD
Places of action
Organizations | Location | People |
---|
article
Structure, microstructure and thermoelectric properties of germanite-type Cu22Fe8Ge4S32 compounds
Abstract
This paper describes the influence of the powder synthesis and densification techniques on the structure, microstructure and thermoelectric properties of Cu22Fe8Ge4S32, a synthetic derivative of the naturally occurring germanite mineral. Two powder synthesis approaches are compared, namely mechanical alloying and conventional sealed tube synthesis, combined with two densification methods spark plasma sintering and hot pressing. Structural analyses by Le Bail refinement of X-ray powder diffraction patterns and transmission electron microscopy confirmed the high crystallinity and the absence of structural defects in the samples. It is especially highlighted that mechanical alloying combined with low sintering temperature allows to reach high purity and to limit the formation of secondary phases due to sulfur volatilization in the bulk specimens. The changes in the electrical resistivity and Seebeck coefficient with the sample preparation methods evidence the high sensitivity of the material to slight stoichiometric deviations. Conversely, the thermal conductivity is less influenced by stoichiometric variations and microstructural changes. This investigation draws attention to the significant impact of powder synthesis and sintering methods on the electrical transport properties of complex quaternary Cu-based sulfides specifically designed to present intrinsically low thermal conductivity for potential thermoelectric applications.