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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Escher, B.
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Topics
Publications (10/10 displayed)
- 2020Phase formation of a biocompatible Ti-based alloy under kinetic constraints studied via in-situ high-energy X-ray diffraction
- 2019Stability of the B2 CuZr phase in Cu-Zr-Al-Sc bulk metallic glass matrix compositescitations
- 2017Structure of glassy Cu<inf>47.5</inf>Zr<inf>47.5</inf>Ag<inf>5</inf> investigated with neutron diffraction with isotopic substitution, X-ray diffraction, EXAFS and reverse Monte Carlo simulationcitations
- 2017Mapping the cyclic plastic zone to elucidate the mechanisms of crack tip deformation in bulk metallic glassescitations
- 2017Influence of the Ag concentration on the medium-range order in a CuZrAlAg bulk metallic glasscitations
- 2016Mapping of residual strains around a shear band in bulk metallic glass by nanobeam X-ray diffractioncitations
- 2016Influence of Ag and Co additions on glass-forming ability, thermal and mechanical properties of Cu–Zr–Al bulk metallic glassescitations
- 2015Structural features of plastic deformation in bulk metallic glassescitations
- 2015Atomic structure and formation of CuZrAl bulk metallic glasses and compositescitations
- 2014Microstructural Evolution and Mechanical Behaviour of Metastable Cu-Zr-Co Alloyscitations
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article
Stability of the B2 CuZr phase in Cu-Zr-Al-Sc bulk metallic glass matrix composites
Abstract
This study investigates the effect, that replacing Zr in a glass-forming Cu47.5Zr47.5Al5 alloy by Sc (0–2 at.%) has on the phase formation as well as on the thermal and mechanical properties. Even though it is not reflected in the thermal data, the glass-forming ability (GFA) is significantly reduced. This originates from the increased tendency to precipitate the shape-memory phase B2 CuZr(Sc), which, in turn, promotes the formation of bulk metallic glass (BMG) matrix composites. Sc appears to be very effective in stabilizing the B2 crystals because it forms the stable B2 CuSc phase with a similar lattice constant like B2 CuZr. By adjusting the casting parameters, the composite microstructure of Cu47.5Zr46.5Al5Sc1 can be controlled to a certain extent. The yield strength and the plasticity of the present composites depend on the crystalline volume fraction. In-situ high-energy X-ray diffraction reveals that deformation proceeds in three stages: (i) martensitic transformation of the B2 phase, (ii) yielding of the amorphous phase and continuing martensitic transformation, (iii) completion of the phase transformation and plastic deformation of all phases. Our work suggests that Sc is a promising candidate to adjust the microstructure and, thus, the mechanical properties of CuZr-based composites consisting of a glassy matrix and shape-memory crystals.