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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Ramasamy, Parthiban
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (16/16 displayed)
- 2023Can Severe Plastic Deformation Tune Nanocrystallization in Fe-Based Metallic Glasses?citations
- 2023Toxic element-free Ti-based metallic glass ribbons with precious metal additionscitations
- 2023Short-range order patterns in Mg66Zn29Ca5 metallic glasscitations
- 2022MEMS-Based in situ electron-microscopy investigation of rapid solidification and heat treatment on eutectic Al-Cucitations
- 2021Evaluation of the Effect of Minor Additions in the Crystallization Path of [(Fe0.5Co0.5)0.75B0.2Si0.05]100-xMx Metallic Glasses by Means of Mössbauer Spectroscopycitations
- 2020Soft Ferromagnetic Bulk Metallic Glass with Potential Self-Healing Abilitycitations
- 2020Structural and Phase Evolution upon Annealing of Fe76Si9−xB10P5Mox (x = 0, 1, 2 and 3) Alloyscitations
- 2019The influence of partial replacement of Cu with Ga on the corrosion behavior of Ti40Zr10Cu36PD14 metallic glassescitations
- 2019The influence of partial replacement of Cu with Ga on the corrosion behavior of Ti 40 Zr 10 Cu 36 PD 14 metallic glassescitations
- 2019Polymorphic Transformation and Magnetic Properties of Rapidly Solidified Fe26.7Co26.7Ni26.7Si8.9B11.0 High-Entropy Alloyscitations
- 2018Soft Ferromagnetic Bulk Metallic Glasses with Enhanced Mechanical Properties
- 2018Thermal behavior, structural relaxation and magnetic study of a new Hf-microalloyed Co-based glassy alloy with high thermal stabilitycitations
- 2017Micro-patterning by thermoplastic forming of Ni-free Ti-based bulk metallic glassescitations
- 2016High pressure die casting of Fe-based metallic glasscitations
- 2016Effect of Cu and Gd on Structural and Magnetic Properties of Fe-Co-B-Si-Nb Metallic Glassescitations
- 2015Structure evolution of soft magnetic (Fe36Co36B19.2Si4.8Nb4)100-xCux (x = 0 and 0.5) bulk glassy alloys
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article
Thermal behavior, structural relaxation and magnetic study of a new Hf-microalloyed Co-based glassy alloy with high thermal stability
Abstract
In the present work, the influence of a minor Hf addition on the atomic structure, crystallization behavior, thermal stability and magnetic properties of a Co-based metallic glass was studied. Thermal analysis indicates that the thermal stability of new glassy ribbons microalloyed with 2.5 at.% Hf is notably enhanced through increasing the incubation time prior to devitrification and enlarging the width of the supercooled liquid region from 72 K to 96 K. Magnetic studies reveal that the new glass exhibits an excellent soft magnetic behavior, i.e., a very low coercivity of 0.26 A/m in the relaxed state, and a comparable saturation magnetization as the Hf-free ribbon. Structural relaxation of the Hf-containing alloy upon isothermal annealing below the glass transition temperature, $T_g$, was investigated by differential scanning calorimetry (DSC) and high-energy synchrotron X-ray diffraction (XRD). The evolution of the recovered enthalpy with annealing time can be expressed by the Kohlrausch-Williams-Watts (KWW) exponential function with a Kohlrausch exponent of 0.88, indicating a broad spectrum of relaxation times. Analysis of the reduced pair correlation functions, G(r), reveals volume shrinkage upon annealing caused by elimination of liquid-like sites including free-volume and anti-free-volume according to the shift in the positions of the G(r) maxima in the medium-range scale. The influence of structural relaxation on the variation of the Curie temperature and the coercivity of the new Hf-microalloyed glassy ribbon is discussed. A faster evolution of the Curie temperature with annealing time compared to the coercivity indicates a preferential dependence of the former on the chemical short-range order (SRO).