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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Eckert, Juergen
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Publications (8/8 displayed)
- 2021Stainless steel reveals an anomaly in thermal expansion behavior of severely deformed materialscitations
- 2019Annealing-assisted high-pressure torsion in $mathrm{Zr_{55}Cu_{30}Al_{10}Ni_{5}}$ metallic glasscitations
- 2017A combined experimental and theoretical investigation of the Al-Melamine reactive milling systemcitations
- 2016In-situ Quasi-Instantaneous e-beam Driven Catalyst-Free Formation Of Crystalline Aluminum Borate Nanowirescitations
- 2014Phase separation in $Zr_{56}-Gd_xCo_{28}Al_{16}$ metallic glasses $(0 ⩽x⩽ 20)$citations
- 2014Room Temperature in Situ Growth of B/BOx Nanowires and BOx Nanotubescitations
- 2013Molecular flexibility and structural instabilities in crystalline L-methioninecitations
- 2010Enhanced pi-pi interactions between a C-60 fullerene and a buckle bend on a double-walled carbon nanotubecitations
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article
A combined experimental and theoretical investigation of the Al-Melamine reactive milling system
Abstract
<p>A versatile ball milling process was employed for the synthesis of hexagonal aluminum nitride (h-AlN) through the reaction of metallic aluminum with melamine. A combined experimental and theoretical study was carried out to evaluate the synthesized products. Milling intermediates and products were fully characterized via various techniques including XRD, FTIR, XPS, Raman and TEM. Moreover, a Boltzmann distribution model was proposed to investigate the effect of milling energy and reactant ratios on the thermodynamic stability and the proportion of different milling products. According to the results, the reaction mechanism and milling products were significantly influenced by the reactant ratio. The optimized condition for AlN synthesis was found to be at Al/M molar ratio of 6, where the final products were consisted of nanostructured AlN with average crystallite size of 11 nm and non-crystalline heterogeneous carbon. (C) 2017 Elsevier B.V. All rights reserved.</p>