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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Brink, Bastian
Technical University of Denmark
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (10/10 displayed)
- 2017The ternary Fe-C-N system: Homogeneous distributions of nitrogen and carboncitations
- 2017The ternary Fe-C-N system: Homogeneous distributions of nitrogen and carboncitations
- 2017On the elusive crystal structure of expanded austenitecitations
- 2017Effect of carbon on interstitial ordering and magnetic properties of ε-Fe2(N,C)1-zcitations
- 2017Effect of carbon on interstitial ordering and magnetic properties of ε-Fe2(N,C) 1-zcitations
- 2016Composition-dependent variation of magnetic properties and interstitial ordering in homogeneous expanded austenitecitations
- 2016On the Carbon Solubility in Expanded Austenite and Formation of Hägg Carbide in AISI 316 Stainless Steelcitations
- 2016On the Carbon Solubility in Expanded Austenite and Formation of Hägg Carbide in AISI 316 Stainless Steelcitations
- 2014Thermal expansion and phase transformations of nitrogen-expanded austenite studied with in situ synchrotron X-ray diffractioncitations
- 2014Thermal expansion and phase transformations of nitrogen-expanded austenite studied with in situ synchrotron X-ray diffractioncitations
Places of action
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article
Effect of carbon on interstitial ordering and magnetic properties of ε-Fe2(N,C)1-z
Abstract
Hexagonal ε-iron nitride and ε-iron carbonitride phases are formed on nitriding and nitrocarburizing ofiron and steel surfaces and can exist in broad compositional ranges. Long-range nitrogen ordering andmagnetic properties for ε-iron nitrides and their dependence on composition have been the focus of several studies. So far, limited attention has been paid to the carbonitrides. In the current work, the effects of substitution of nitrogen by carbon on the interstitial ordering and magnetic properties in Fe2(C,N)<sub>1-z</sub> are explored using neutron diffraction, M€ossbauer spectroscopy and vibrating samplemagnetometry. Neutron diffraction patterns showed 001 and 301 superstructure reflections, confirminga previously proposed structural model in space group P31m (compared to P6<sub>3</sub>22 for the pure nitrides).On partial substitution of nitrogen by carbon in ε-iron nitride the Curie temperature, the saturationmagnetization and the hyperfine fields of the iron atoms are increased, while isomer shifts are decreased.The effects on the a and c lattice parameters indicate a change in interstitial ordering, which is related tomore favorable interactions between a nitrogen and carbon atom than among nitrogen atoms. Thisinteraction leads to additional interstitial (short-range) ordering and a decrease in the c lattice parameter,while the a lattice parameter is largely unaffected.