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Debski, A.
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Publications (4/4 displayed)
- 2020Experimental and ab initio study of the Ag-Li system for energy storage and high-temperature solderscitations
- 2018Formation enthalpy of Ga-Li intermetallic phases. Experiment vs. calculationscitations
- 2014Li-Si phase diagram: Enthalpy of mixing, thermodynamic stability, and coherent assessmentcitations
- 2014Optimization and assessment of the Ag-Ca phase diagramcitations
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article
Optimization and assessment of the Ag-Ca phase diagram
Abstract
The Ag-Ca phase diagram was optimized and subsequently assessed. New data for the enthalpies of formation of the Ag9Ca2 and AgCa3 compounds were obtained by means of drop calorimetiy. Differential Thermal Analysis experiments were also performed and the resulting concentration/transformation temperatures could be compared with the phase diagram. First principles calculations were performed leading to the Gibbs free energies of each compound as a function of temperature. Tentative structures with possibility of being stable were found for Ag5Ca and AgCa3 compounds. Finally, the CALPHAD method was used to assess the phase diagram as well as all the available results.